GCMS calibration table for TCLP analysis, Dec 2001

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Library Search Compound Report

Data File C:\HPCHEM\1\DATA\DEC0 6 01\LBA.D Vial: 10 Acq On 6 Dec 2001 6:23 pm Operator: GALOS Sample gc/ms unknown 11/7 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP112701.M (RTE Integrator) Title : 208 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 2-Butanol, 3-methyl-, (S)- Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.

7.21 11.26 ng/uL 2874870 1,4-Dichlorobenzene-d4 11.89

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Butanol, 3- methyl-, (S)- 88 C5H120 001517-66-4 42 2 1,2-Propanediol, 3-methoxy- 106 C4H10O3 000623-39-2 36 3 2,3 -Butanediol 90 C4H10O2 000513-85-9 33 4 N-Ethylformamide 73 C3H7NO 000627-45-2 9 Abundance Scan 258 (7.205 min): LBA.D (-) m/z 45.0,5 100.00% 45

5000 61 73 ' i ' 1 । । . . . . । . i . . । . i 1 । । 1 1 88 6.80 7.00 7.20 7.40 7.60 TTIgg 207 m/z 43.0,0 64.64% miz-> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 Abundance #852:2-Butanol, 3-methyl-, (S)- 45

5000 ‘ • i * IIIr T Ir T’ I 1 1 6.80 7.00 7.20 7.40 7.60 55 73 m/ z 73.0.5 36.28%

m/z-> mmpm 27 +_87 102030405060708090 100110120130140150160170180190200210 Abundance #63660 1,2-Propanediol, 3-methoxy- 45 • J ■ • ■ • | • k • | ■ TT I | 1 1 I . | 1 1 ■ 6.80 7.00 7.20 7.40 7.60 5000 75 m/z 61.10 35.78% 31 61 15 I 88 mpmpmmm TpmgT miz-____ 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 Abundance #917: 2,3-Butanediol I i TT - 45 6.80 7.00 7.20 7.40 7.60 m/z 44.10 13.06% 5000

29 19 57 75 90 rm mm ।11 । i।।i।।j.... 11111 | 11 n 11111 [ 1111111 r m/z~> 10 20 30 40 50 60 70 80 90 100110120130140150160170180190200210 6.80 7.00 7.20 7.407.80

LBA.D NP112701.M Wed Dec 19 13:08:50 2001 Page 3

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