GC/MS results for unknown compounds and surrogates, sample AE10981, May

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Data File : C:\MSDCHEM\1\DATA\051402\10981.D Vial: 10 Acq On : 14 May 2002 8:50 pm Operator: Mclean Sample : 5/10 kb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 4 Benzene, 1,2,3,5-tetrachlor... Concentration Rank 12

R.T. EstConc Area Relative to ISTD R.T.

21.40 0.21 ug/L 272474 Phenanthranerie-dl0 22.96

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Benzene, 1,2,3,5-tetrachloro-4,6... 242 C8H6C14 000877-09-8 98‘ 2 2-Chloroaniline-5-sulfonic acid 207 C6H6C1NO3SI 000098-36-2 43 3 Quinoline, 3-bromo- 207 C9H6BrN 005332-24-1 38 4 Quinoline, 3-bromo- 207 C9H6BrN 005332-24-1 38 Abundance Scan 3117 (21.394 min): 10981 .D (-3106) (-) im/z 207.00 100.00% 207

244 5000 136 WN Wyw/ 85

+ 1’11 I** i—r-j-i—i—r-r-j-r 172 229

miz-> 0! t ‘I 20 32111744 40 60 80 I 102 120 I . , III,I, JI + 100 120 I ■ 1 i 1 ' 140 200 160 180 220 240 | 21.00 21.20 21.40 21.60 21.80 m/ z 2 08.90 88.73%

Abundance #84890: Benzene, 1,2,3,5-tetrachloro-4,6-dimethyl- 207 244 A _h 5000 r1 ' ■ ' 1 1 ’ —/MA 136 21.00 21.20 21.40 21.60 21.80 m/z 243.90 49.30% 51 B 74 85 00 171 163 4,1.1,170121..IL 0 i ■ ■ ■ - । < 1 * ' I' TII . 157 l .193 , 229 1 m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #84878: 2-Chloroaniline-5-sulfonic acid 207 ..... ,........ 1, 21.00 21.20 21.40 21.60 21.80 5000 m/z 136.00 43.83%

43 90 ........................................................................................... ....................... 0 ...... ill i ■ ■ ■ ■ । । I ■! T | f I1 ‘r ""T T i "i1 "I i i Tdu i > , i । i i , i i i i । i । । i । ....... I i । i i । > । i : iz-> 20 40 60 80 100 120 140 160 180 200 220 240 Abundance #84880: Quinoline, 3-bromo- 128 207 21.00 21.20 21.40 21.60 21.80 m/z 241.90 38.59%

5000 101 75 50 64 on 0 | 27.38, 1 —-44117.141152 181 . - i ■ ■ ■ ■ i . ■ ■ ■ i ■ m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 21.00 21.20 21.40 21.60 21.80

10981.D 050102.M Thu May 16 14:37:14 2002 Page 7

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