GCMS calibration data for TCLP method, May 2002

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Data File C:\HPCHEM\l\DATA\MAY0302\9572.D Vial: 46 Acq On 5 May 2002 12:06 pm Operator: Sample GC/MS SCAN 4/23 FB Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 8.16 13.06 ug/1 937276 1,4-Dichlorobenzene-d4 12.19 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pentanone, 4-hydroxy-4-methyl- 116 C6H1202 000123-42-2 64 2 Acetic acid, 1,1-dimethylethyl este 116 C6H12O2 000540-88-5 9 3 CH2=CHCK2C(0)OCH3 100 C5H802 003724-55-8 9 4 5-Hexen-2-one 98 C6H10O 000109-49-9 7 Abundance Scan 341 (8.162 min): 9572.D (-) m/z 43.05 100.00% 43

5000 59

101 7 80 8.00 8.20 8.40 8.60

miz-> ................... i ■ ‘ 10 ' i 1 1 ' ' i ‘ 20 30 ,I, . , , ,3?" 40 +53+ 50 —ITITT 60 69 70 80 83 90 100 0 110 m/z 59.10 42.04% Abundance #64274:2-Pentanone, 4-hydroxy-4-methyl- 43

5000 59 7.80 8.00 8.20 8.40 8.60 m/z 58.10 16.90% 27 101

miz—> 10 20 11 30 ....... 40 +49+ 50 60 I ■ ■ ■ ■ i

70 80 83 1 ■ ■ ■ i • '■ ■ ■ i ■ ■ ■

90 , I■ ■ ■ ■ i ■ 1 i

100 110 Abundance #3292: Acetic acid, 1,1-dimethylethyl ester 43 7.80 8.00 8.20 8.40 8.60 5000 57 m/z 101.15 13.72%| 101 15 27 I ' ' i ' ' ' ■ i ' ' ' ' i ■ ‘ ' ■ i ' ■ 1 1 1 'i' 1 ' ■ i ' ' ' 1 1 1 1 ' ' I ' 1 1 ' I1 1 1 ' I ' mfz-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1448: CH2=CHCH2C(O)OCH3 43 7.80 8.00 8.20 8.40 8.60 m/z 41.05 7.08% 5000

58 72 100 ..................... 381 I 1 ' ' ' I 1 ' ' ' I ' ' ■ ' r1 TITTITI TTuu—rmOTTmT m/z—> 10 20 30 40 50 60 70 80 90 100 110 7.80 8.00 8.20 8.40 8.60

9572.D GCMS0501.M Tue May 07 15:00:53 2002 Page 1

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