Volatile organic compounds blank results, Mar 1 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed) Data File : C:\HPCHEM\l\DATA\02MAR01\0301C10B.D Vial: 31 Acq On : 2 Mar 2002 10:59 am Operator: Sample : cal 10 Inst : 210 Mise : March 1, 2002 Multiplr: 1.00 MS Integration Params: GAS5.P Quant Time: Mar 5 8:34 2002 Quant Results File: HP021102.RES Quant Method : C:\HPCHEM\1\METHODS\HP021102.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Mon Mar 04 11:29:42 2002 Response via : Initial Calibration DataAcq Meth : HP021102

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.58 114 692765 5.00 ug/L 0.00 21) CHLOROBENZENE-D5 23.34 82 334708 5.00 ug/L 0.00 49) 1,4-DICHLOROBENZENE-D4 29.39 152 282197 5.00 ug/L 0.00 System Monitoring Compounds 2) 1,2-Dichloroethane-d4 14.63 65 168240 5.72 ug/L 0.00 Spiked Amount 5.000 Recovery = 114.40% 22) Toluene-d8 19.49 98 869855 5.14 ug/L 0.00 Spiked Amount 5.000 Recovery = 102.80% 50) 4-Bromofluorobenzene 26.39 95 299709 5.08 ug/L 0.00 Spiked Amount 5.000 Recovery = 101.60%

Target Compounds Qvalue 3) DICHLORODIFLUOROMETHANE 4.21 85 270165 7.77 ug/L 98 4) CHLOROMETHANE 4.85 50 324302 8.28 ug/L 97 5) VINYL CHLORIDE 4.89 62 494203 9.92 ug/L 99 6) BROMOMETHANE 5.75 96 250682 7.92 ug/L 98 7) CHLOROETHANE 5.87 64 262322 8.55 ug/L 98 8) TRICHLOROFLUOROMETHANE 6.40 101 566914 12.43 ug/L 99 10) 1,1-DICHLOROETHENE 7.79 61 524397 8.13 ug/L 91 11) METHYLENE CHLORIDE 8.98 49 562864 9.36 ug/L 90 12) METHYL TERT BUTYL ETHER 9.29 73 779320 9.58 ug/L 98 13) TRANS-1,2-DICHLOROETHENE 9.73 61 615128 9.35 ug/L 93 14) 1,1-DICHLOROETHANE 10.81 63 797422 9.98 ug/L 98 15) 2-BUTANONE (MEK) 12.25 43 37006 14.05 ug/L 97 16) 2,2-DICHLOROPROPANE 12.26 77 392788 6.73 ug/L 97 17) CIS-1,2-DICHLOROETHENE 12.40 61 637994 10.19 ug/L 92 18) CHLOROFORM 12.79 83 767784 10.03 ug/L 99 19) BROMOCHLOROMETHANE 13.25 49 296000 10.18 ug/L 93 20) 1,2-DICHLOROETHANE 16.90 62 322603 9.79 ug/L 98 23) 1,1,1-TRICHLOROETHANE 13.82 97 604444 10.58 ug/L 99 24) 1,1-DICHLOROPROPENE 14.22 75 614174 10.13 ug/L 98 25) CARBON TETRACHLORIDE 14.49 117 413730 9.78 ug/L 100 26) BENZENE 14.92 77 476056 9.56 ug/L 96 27) TRICHLOROETHENE 16.47 95 470055 9.98 ug/L 99 28) 1,2-DICHLOROPROPANE 16.90 63 461053 10.18 ug/L 99 29) DIBROMOMETHANE 17.67 174 142257 9.84 ug/L 93 30) BROMODICHLOROMETHANE 17.50 83 444502 9.66 ug/L 98 31) 2-CHLOROETHYL VINYL ETHER 19.69 63 166532 10.87 ug/L 90 32) METHYL ISO-BUTYL KETONE 18.32 58 48354 8.04 ug/L 77

(#) = qualifier out of range (m) = manual integration 0301C10B.D HP021102.M Tue Mar 05 08:34:48 2002 Page 1

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