Volatile organic compounds blank results, Feb 28 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed) Data File : C:\HPCHEM\1\DATA\02FEB27\0227C10.D Vial: 4 Acq On : 27 Feb 2002 11:57 am Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Feb 27 13:41 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Feb 19 16:16:43 2002 Response via : Initial Calibration DataAcq Meth : HP021702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.17 114 3689789 5.00 ug/L 0.00 24) CHLOROBENZENE-D5 21.83 117 3717169 5.00 ug/L 0.00 52) 1,4-DICHLOROBENZENE-D4 27.00 152 1904386 5.00 ug/L 0.00 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.40 65 1223939 4.46 ug/L 0.00 Spiked Amount 5.000 Recovery = 89.20% 3) 4-BROMOFLUOROBENZENE 24.42 174 1449471 5.18 ug/L 0.00 Spiked Amount 5.000 Recovery = 103.60% 25) TOLUENE-D8 18.52 98 4546122 4.93 ug/L 0.00 Spiked Amount 5.000 Recovery = 98.60% Target Compounds Ovalue 4) DICHLORODIFLUOROMETHANE 4.89 85 826913 6.86 ug/L 100 5) CHLOROMETHANE 5.52 50 904969 12.01 ug/L 98 6) VINYL CHLORIDE 5.64 62 498382 10.72 ug/L 93 7) BROMOMETHANE 6.63 94 606156 10.66 ug/L 94 8) CHLOROETHANE 6.77 64 548859 9.34 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.34 101 1265787 11.09 ug/L 98 10) Isopropyl Alcohol 7.85 45 9231 4.44 ug/L 54 12) ACETONE 8.31 43 182964 7.66 ug/L 96 13) 1,1-DICHLOROETHENE 8.67 61 1688850 9.66 ug/L 98 14) METHYLENE CHLORIDE 9.67 49 2011682 9.75 ug/L 98 15) METHYL TERT BUTYL ETHER 9.98 73 2117923 9.41 ug/L 99 16) TRANS-1,2-DICHLOROETHENE 10.34 61 2044338 9.45 ug/L 99 17) 1,1-DICHLOROETHANE 11.24 63 2481431 9.68 ug/L 98 18) 2-BUTANONE (MEK) 12.06 43 368383 7.06 ug/L 94 19) 2,2-DICHLOROPROPANE 12.45 77 1784999 8.89 ug/L 99 2 0) CIS-1,2-DICHLOROETHENE 12.55 96 1593548 10.74 ug/L 98 21) CHLOROFORM 12.89 83 2616594 10.12 ug/L 99 22) BROMOCHLOROMETHANE 13.26 49 1294824 10.48 ug/L 96 23) 1,2-DICHLOROETHANE 14.61 62 1676922 9.72 ug/L 96 26) 1,1,1-TRICHLOROETHANE 13.77 97 1839260 9.32 ug/L 99 27) 1,1-DICHLOROPROPENE 14.10 75 1883490 9.56 ug/L 99 28) CARBON TETRACHLORIDE 14.35 117 1558657 9.68 ug/L 99 29) BENZENE 14.69 78 5335559 10.28 ug/L 100 30) TRICHLOROETHENE 15.97 95 1551850 10.03 ug/L 98 31) 1,2-DICHLOROPROPANE 16.33 63 1532590 10.45 ug/L 99 32) DIBROMOMETHANE 17.01 174 804990 11.40 ug/L 95 33) BROMODICHLOROMETHANE 16.86 83 1930861 10.36 ug/L 99 34) 2-CHLOROETHYL VINYL ETHER 17.33 63 505351 9.50 ug/L 99 35) METHYL ISO-BUTYL KETONE 17.40 58 288394 10.73 ug/L 92 36) CIS-1,3-DICHLOROPROPENE 17.95 75 2140358 10.42 ug/L 98 37) TOLUENE 18.69 91 5839011 10.69 ug/L 99 3 8) TRANS-1,3-DICHLOROPROPENE 18.97 75 1532701 10.22 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.36 97 1012165 11.34 ug/L 98 40) TETRACHLOROETHENE 20.14 166 1601880 10.72 ug/L 99 41) 1,3-DICHLOROPROPANE 19.89 76 1847923 10.73 ug/L 99 42) DIBROMOCHLOROMETHANE 20.58 129 1209522 11.35 ug/L 99 43) 1,2-DIBROMOETHANE 21.03 107 1043590 10.89 ug/L 99 44) CHLOROBENZENE 21.91 112 3985870 11.37 ug/L 99 45) 1,1,1,2-TETRACHLOROETHANE 21.96 131 1322514 11.28 ug/L 99 46) 2-HEXANONE 19.26 43 732288 13.17 ug/L 98 47) ETHYLBENZENE 21.95 91 6842068 10.91 ug/L 99 (#) = qualifier out of range (m) = manual integration 0227C10.D HP021102.M Wed Mar 06 13:48:41 2002 Page 1

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