Volatile organic compounds blank results, Mar 8 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File C:\HPCHEM\l\DATA\02mar08\0308C10.D Vial: 2 Acq On 8 Mar 2002 11:47 am Operator: 201-wb Sample cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 8 12:25 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.03 114 1425066 5.00 ug/L -0.14 24) CHLOROBENZENE-D5 21.69 117 1361397 5.00 ug/L -0.14 52) 1,4-DICHLOROBENZENE-D4 26.87 152 672566 5.00 ug/L -0.14

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.27 65 552609 6.00 ug/L -0.14 Spiked Amount 5.000 Recovery = 120.00% 3) 4-BROMOFLUOROBENZENE 24.28 174 525629 4.56 ug/L -0.14 Spiked Amount 5.000 Recovery = 91.20% 25) TOLUENE-D8 18.39 98 1736703 5.29 ug/L -0.14 Spiked Amount 5.000 Recovery = 105.80%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.84 85 304560 7.87 ug/L 97 5) CHLOROMETHANE 5.44 50 355425 8.43 ug/L 97 6) VINYL CHLORIDE 5.56 62 187682 7.95 ug/L 95 7) BROMOMETHANE 6.55 94 286408 10.64 ug/L 96 8) CHLOROETHANE 6.68 64 270724 11.44 ug/L 93 9) TRICHLOROFLUOROMETHANE 7.23 101 499459 9.56 ug/L 98 11) 1,1,2-Trichloro-1,2,2-trif 8.12 101 329023 14.82 ug/L 100 12) ACETONE 8.21 43 109248 14.98 ug/L 99 13) 1,1-DICHLOROETHENE 8.55 61 901047 14.52 ug/L 96 14) METHYLENE CHLORIDE 9.55 49 1087759 14.87 ug/L 99 15) METHYL TERT BUTYL ETHER 9.86 73 851347 10.15 ug/L 99 16) TRANS-1,2-DICHLOROETHENE 10.22 61 949254 11.28 ug/L 99 17) 1,1-DICHLOROETHANE 11.10 63 1099911 10.58 ug/L 99 18) 2-BUTANONE (MEK) 11.94 43 163414 10.47 ug/L 94 19) 2,2-DICHLOROPROPANE 12.33 77 849040 11.08 ug/L 97 20) CIS-1,2-DICHLOROETHENE 12.41 96 660335 10.33 ug/L 96 21) CHLOROFORM 12.75 83 1146063 10.50 ug/L 99 22) BROMOCHLOROMETHANE 13.13 49 495483 9.21 ug/L 98 23) 1,2-DICHLOROETHANE 14.47 62 757548 10.99 ug/L 100 26) 1,1,1-TRICHLOROETHANE 13.64 97 864128 11.87 ug/L 98 27) 1,1-DICHLOROPROPENE 13.96 75 861470 12.07 ug/L 97 28) CARBON TETRACHLORIDE 14.23 117 743447 12.17 ug/L 99 29) BENZENE 14.57 78 2165800 10.73 ug/L 99 30) TRICHLOROETHENE 15.83 95 666833 11.23 ug/L 97 31) 1,2-DICHLOROPROPANE 16.19 63 578538 9.88 ug/L 99 32) DIBROMOMETHANE 16.87 174 283474 9.22 ug/L 93 33) BROMODICHLOROMETHANE 16.72 83 795458 10.82 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.20 63 192857 10.38 ug/L 99 35) METHYL ISO-BUTYL KETONE 17.28 58 91686 8.78 ug/L 95 36) CIS-1,3-DICHLOROPROPENE 17.81 75 820372 10.26 ug/L 97 37) TOLUENE 18.56 91 2349191 10.59 ug/L 100 38) TRANS-1,3-DICHLOROPROPENE 18.85 75 603278 10.55 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.22 97 367014 9.63 ug/L 99 40) TETRACHLOROETHENE 20.00 166 642371 10.08 ug/L 97 41) 1,3-DICHLOROPROPANE 19.75 76 691150 9.89 ug/L 99 42) DIBROMOCHLOROMETHANE 20.45 129 456239 9.97 ug/L 99 43) 1,2-DIBROMOETHANE 20.89 107 371060 9.56 ug/L 97 44) CHLOROBENZENE 21.78 112 1528987 10.05 ug/L 97 45) 1,1,1,2-TETRACHLOROETHANE 21.83 131 512773 10.17 ug/L 96 46) 2-HEXANONE 19.12 43 164244 6.18 ug/L 90 47) ETHYLBENZENE 21.81 91 2772671 11.01 ug/L 100 (#) = qualifier out of range (m) = manual integration 0308C10.D HP022702.M Fri Mar 08 12:25:57 2002 Page 1

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