Volatile organic compounds results, Mar 7 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File C: \HPCHEM\ 1 \DATA\ 02mar07 \ 03 07C10 . D Vial: 2 Acq On 7 Mar 2002 9:22 am Operator: 201-wb Sample cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 7 10:00 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.05 114 1690408 5.00 ug/L -0.12 24) CHLOROBENZENE-D5 21.71 117 1597098 5.00 ug/L -0.12 52) 1,4-DICHLOROBENZENE-D4 26.88 152 767511 5.00 ug/L -0.12 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.29 65 627404 5.74 ug/L -0.12 Spiked Amount 5.000 Recovery = 114.80% 3) 4-BROMOFLUOROBENZENE 24.30 174 575562 4.21 ug/L -0.12 Spiked Amount 5.000 Recovery = 84.20% 25) TOLUENE-D8 18.41 98 2066898 5.37 ug/L -0.12 Spiked Amount 5.000 Recovery = 107.40% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 420898 9.04 ug/L 97 5) CHLOROMETHANE 5.45 50 421559 8.43 ug/L 97 6) VINYL CHLORIDE 5.57 62 209869 7.44 ug/L 92 7) BROMOMETHANE 6.56 94 308785 9.73 ug/L 93 8) CHLOROETHANE 6.70 64 296217 10.58 ug/L 97 9) TRICHLOROFLUOROMETHANE 7.25 101 534505 8.62 ug/L 99 11) l,l,2-Trichloro-l,2,2-trif 8.14 101 408922 15.53 ug/L 97 12) ACETONE 8.23 43 132445 15.31 ug/L 95 13) 1,1-DICHLOROETHENE 8.57 61 1030490 14.00 ug/L 97 14) METHYLENE CHLORIDE 9.57 49 1271220 14.65 ug/L 99 15) METHYL TERT BUTYL ETHER 9.88 73 997737 10.03 ug/L 100 16) TRANS-1,2-DICHLOROETHENE 10.23 61 1111064 11.13 ug/L 97 17) 1,1-DICHLOROETHANE 11.14 63 1275081 10.34 ug/L 98 18) 2-BUTANONE (MEK) 11.95 43 198712 10.73 ug/L 90 19) 2,2-DICHLOROPROPANE 12.35 77 988472 10.88 ug/L 96 20) CIS-1,2-DICHLOROETHENE 12.43 96 758261 10.00 ug/L 94 21) CHLOROFORM 12.77 83 1334098 10.30 ug/L 99 22) BROMOCHLOROMETHANE 13.15 49 583803 9.15 ug/L 95 23) 1,2-DICHLOROETHANE 14.49 62 879507 10.75 ug/L 100 26) 1,1,1-TRICHLOROETHANE 13.66 97 994253 11.64 ug/L 99 27) 1,1-DICHLOROPROPENE 13.98 75 1016176 12.14 ug/L 97 28) CARBON TETRACHLORIDE 14.25 117 846901 11.82 ug/L 99 29) BENZENE 14.59 78 2577355 10.88 ug/L 99 30) TRICHLOROETHENE 15.87 95 775962 11.14 ug/L 99 31) 1,2-DICHLOROPROPANE 16.21 63 689708 10.04 ug/L 98 32) DIBROMOMETHANE 16.89 174 334926 9.29 ug/L 92 33) BROMODICHLOROMETHANE 16.74 83 933351 10.82 ug/L 99 34) 2-CHLOROETHYL VINYL ETHER 17.21 63 234917 10.78 ug/L 97 35) METHYL ISO-BUTYL KETONE 17.30 58 113130 9.23 ug/L 97 36) CIS-1,3-DICHLOROPROPENE 17.83 75 986096 10.51 ug/L 98 37) TOLUENE 18.59 91 2774106 10.66 ug/L 100 38) TRANS-1,3-DICHLOROPROPENE 18.87 75 711958 10.61 ug/L 99 39) 1,1,2-TRICHLOROETHANE 19.24 97 431191 9.64 ug/L 99 40) TETRACHLOROETHENE 20.02 166 750071 10.04 ug/L 97 41) 1,3-DICHLOROPROPANE 19.79 76 822248 10.03 ug/L 98 42) DIBROMOCHLOROMETHANE 20.47 129 536745 10.00 ug/L 100 43) 1,2-DIBROMOETHANE 20.93 107 443291 9.73 ug/L 96 44) CHLOROBENZENE 21.79 112 1802432 10.10 ug/L 97 45) 1,1,1,2-TETRACHLOROETHANE 21.85 131 605800 10.24 ug/L 97 46) 2-HEXANONE 19.14 43 205302 6.58 ug/L 89 47) ETHYLBENZENE 21.85 91 3244992 10.98 ug/L 100 (#) = qualifier out of range (m) = manual integration 0307C10.D HP022702.M Thu Mar 07 10:00:57 2002 Page 1

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