VOC analysis results, sample AE03507, Feb 22 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed) Data File : C:\HPCHEM\1\DATA\02FEB26\0226C10.D Vial: 2 Acq On : 26 Feb 2002 3:48 pm Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Feb 27 14:25 2002 Quant Results File: HP021702.RES Quant Method : C:\HPCHEM\1\METHODS\HP021702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Feb 19 16:16:43 2002 Response via : Initial Calibration DataAcq Meth : HP021702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.14 114 2654228 5.00 ug/L 0.02 24) CHLOROBENZENE-D5 21.81 117 2740618 5.00 ug/L 0.05 52) 1,4-DICHLOROBENZENE-D4 26.99 152 1457968 5.00 ug/L 0.04 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.37 65 933250 4.62 ug/L 0.02 Spiked Amount 5.000 Recovery = 92.40% 3) 4-BROMOFLUOROBENZENE 24.40 174 1100452 5.52 ug/L 0.04 Spiked Amount 5.000 Recovery = 110.40% 25) TOLUENE-D8 18.51 98 3273962 4.82 ug/L 0.04 Spiked Amount 5.000 Recovery = 96.40%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.86 85 753067 8.05 ug/L 99 5) CHLOROMETHANE 5.55 50 1136084 15.68 ug/L 99 6) VINYL CHLORIDE 5.75 62 482018 12.67 ug/L 96 7) BROMOMETHANE 6.59 94 640292m 14.81 ug/L 8) CHLOROETHANE 6.74 64 693779 15.89 ug/L 96 9) TRICHLOROFLUOROMETHANE 7.30 101 1354088 16.15 ug/L 100 12) ACETONE 8.28 43 170219 9.33 ug/L 96 13) 1,1-DICHLOROETHENE 8.63 61 1252641 9.82 ug/L 98 14) METHYLENE CHLORIDE 9.64 49 1221513 7.97 ug/L 97 15) METHYL TERT BUTYL ETHER 9.94 73 1868681 11.03 ug/L 98 16) TRANS-1,2-DICHLOROETHENE 10.30 61 1845845 11.31 ug/L 95 17) 1,1-DICHLOROETHANE 11.20 63 2239845 11.62 ug/L 100 18) 2-BUTANONE (MEK) 12.04 43 358821 8.49 ug/L 98 19) 2,2-DICHLOROPROPANE 12.41 77 1781597 11.51 ug/L 97 20) CIS-1,2-DICHLOROETHENE 12.52 96 1448917 13.15 ug/L 92 21) CHLOROFORM 12.86 83 2334209 12.05 ug/L 99 22) BROMOCHLOROMETHANE 13.23 49 1167307 12.67 ug/L 93 23) 1,2-DICHLOROETHANE 14.58 62 1526655 11.71 ug/L 99 26) 1,1,1-TRICHLOROETHANE 13.74 97 1791174 11.72 ug/L 97 27) 1,1-DICHLOROPROPENE . 14.06 75 1829497 12.00 ug/L 98 28) CARBON TETRACHLORIDE 14.34 117 1522499 12.25 ug/L 99 29) BENZENE 14.68 78 4819384 12.17 ug/L 100 30) TRICHLOROETHENE 15.95 95 1424175 12.03 ug/L 91 31) 1,2-DICHLOROPROPANE 16.31 63 1349707 12.06 ug/L 96 32) DIBROMOMETHANE 16.98 174 749399 14.11 ug/L 91 33) BROMODICHLOROMETHANE 16.82 83 1738288 12.14 ug/L 96 34) 2-CHLOROETHYL VINYL ETHER 17.30 63 496991 12.01 ug/L 100 35) METHYL ISO-BUTYL KETONE 17.38 58 282230 13.77 ug/L 95 36) CIS-1,3-DICHLOROPROPENE 17.91 75 1957707 12.40 ug/L 100 37) TOLUENE 18.68 91 5302399 12.81 ug/L 99 3 8) TRANS-1,3-DICHLOROPROPENE 18.95 75 1429439 12.36 ug/L 98 39) 1,1,2-TRICHLOROETHANE 19.34 97 919445 13.71 ug/L 98 40) TETRACHLOROETHENE 20.13 166 1536699 13.64 ug/L 97 41) 1,3-DICHLOROPROPANE 19.87 76 1718563 13.08 ug/L 99 42) DIBROMOCHLOROMETHANE 20.57 129 1106340 13.72 ug/L 100 43) 1,2-DIBROMOETHANE 21.01 107 964137 13.27 ug/L 94 44) CHLOROBENZENE 21.90 112 3529870 13.37 ug/L 95 45) 1,1,1,2-TETRACHLOROETHANE 21.95 131 1180650 13.34 ug/L 97 46) 2-HEXANONE 19.22 43 528290 12.84 ug/L 96 47) ETHYLBENZENE 21.93 91 6145047 12.89 ug/L 96 48) P & M-XYLENE 22.08 106 4476518 27.51 ug/L 89 (#) = qualifier out of range (m) = manual integration 0226C10.D HP021702.M Wed Feb 27 14:25:52 2002 Page 1

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