VOC analysis results, sample AE03958, Feb 19 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02FEB19\0219C10B.D Vial: 6 Acq On : 19 Feb 2002 2:39 pm Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise : February 19, 2002 Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Feb 19 16:17 2002 Quant Results File: HP021702.RES Quant Method : C:\HPCHEM\1\METHODS\HP021702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Feb 19 16:16:43 2002 Response via : Initial Calibration DataAcq Meth : HP021702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.07 114 1786728 5.00 ug/L -0.04 24) CHLOROBENZENE-D5 21.72 117 1688049 5.00 ug/L -0.04 52) 1,4-DICHLOROBENZENE-D4 26.90 152 800492 5.00 ug/L -0.05 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.30 65 605949 4.45 ug/L -0.04 Spiked Amount 5.000 Recovery = 89.00% 3) 4-BROMOFLUOROBENZENE 24.31 174 596424 4.44 ug/L -0.04 Spiked Amount 5.000 Recovery = 88.80% 25) TOLUENE-D8 18.42 98 2181802 5.21 ug/L -0.05 Spiked Amount 5.000 Recovery = 104.20% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.85 85 448777 7.13 ug/L 99 5) CHLOROMETHANE 5.47 50 466445 9.72 ug/L 99 6) VINYL CHLORIDE 5.59 62 259901 10.62 ug/L 98 7) BROMOMETHANE 6.56 94 281100 9.66 ug/L 99 8) CHLOROETHANE 6.71 64 292904 9.96 ug/L 96 9) TRICHLOROFLUOROMETHANE 7.26 101 559116 9.90 ug/L 99 12) ACETONE 8.22 43 95670 7.79 ug/L 91 13) 1,1-DICHLOROETHENE 8.58 61 786668 9.16 ug/L 99 14) METHYLENE CHLORIDE 9.59 49 1035651 10.04 ug/L 98 15) METHYL TERT BUTYL ETHER 9.88 73 969670 8.50 ug/L 95 16) TRANS-1,2-DICHLOROETHENE 10.25 61 1076561 9.80 ug/L 100 17) 1,1-DICHLOROETHANE 11.14 63 1290876 9.95 ug/L 97 18) 2-BUTANONE (MEK) 11.97 43 198631 6.98 ug/L 100 19) 2,2-DICHLOROPROPANE 12.34 77 973588 9.35 ug/L 98 20) CIS-1,2-DICHLOROETHENE 12.45 96 755089 10.18 ug/L 96 21) CHLOROFORM 12.79 83 1271781 9.75 ug/L 100 22) BROMOCHLOROMETHANE 13.16 49 626773 10.10 ug/L 97 23) 1,2-DICHLOROETHANE 14.51 62 794496 9.05 ug/L 97 26) 1,1,1-TRICHLOROETHANE 13.67 97 953935 10.13 ug/L 97 27) 1,1-DICHLOROPROPENE 14.00 75 1019236 10.85 ug/L 98 28) CARBON TETRACHLORIDE 14.25 117 794392 10.38 ug/L 97 29) BENZENE 14.59 78 2642390 10.84 ug/L 99 30) TRICHLOROETHENE 15.87 95 776221 10.65 ug/L 96 31) 1,2-DICHLOROPROPANE 16.23 63 752136 10.91 ug/L 97 32) DIBROMOMETHANE 16.91 174 329479 10.07 ug/L 94 33) BROMODICHLOROMETHANE 16.75 83 912157 10.34 ug/L 98 34) 2-CHLOROETHYL VINYL ETHER 17.23 63 247271 9.70 ug/L 100 35) METHYL ISO-BUTYL KETONE 17.30 58 125145 9.92 ug/L 97 36) CIS-1,3-DICHLOROPROPENE 17.84 75 1045080 10.75 ug/L 99 37) TOLUENE 18.59 91 2823031 11.08 ug/L 98 3 8) TRANS-1,3-DICHLOROPROPENE 18.86 75 733841 10.30 ug/L 97 39) 1,1,2-TRICHLOROETHANE 19.26 97 437231 10.59 ug/L 99 40) TETRACHLOROETHENE 20.04 166 768848 11.08 ug/L 96 41) 1,3-DICHLOROPROPANE 19.78 76 842187 10.41 ug/L 97 42) DIBROMOCHLOROMETHANE 20.48 129 521245 10.49 ug/L 98 43) 1,2-DIBROMOETHANE 20.92 107 450662 10.07 ug/L 94 44) CHLOROBENZENE 21.81 112 1857367 11.42 ug/L 94 45) 1,1,1,2-TETRACHLOROETHANE 21.86 131 595763 10.93 ug/L 97 46) 2-HEXANONE 19.15 43 241224 9.52 ug/L 95 47) ETHYLBENZENE 21.84 91 3318590 11.30 ug/L 98 48) P & M-XYLENE 22.00 106 2268049 22.63 ug/L 93 (#) = qualifier out of range (m) = manual integration 0219C10B.D HP021702.M Wed Feb 20 10:09:57 2002 Page 1

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