Volatile organic compounds results, Mar 6 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File : C:\HPCHEM\1\DATA\02mar06\0306C10.D Vial: 2 Acq On : 6 Mar 2002 9:23 am Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise : March 6, 2002 Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Mar 6 10:02 2002 Quant Results File: HP022702.RES Quant Method : C:\HPCHEM\1\METHODS\HP022702.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Tue Mar 05 13:20:57 2002 Response via : Initial Calibration DataAcq Meth : HP022702

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.05 114 1353523 5.00 ug/L -0.12 24) CHLOROBENZENE-D5 21.71 117 1355725 5.00 ug/L -0.12 52) 1,4-DICHLOROBENZENE-D4 26.88 152 688336 5.00 ug/L -0.12 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.28 65 537440 6.14 ug/L -0.12 Spiked Amount 5.000 Recovery = 122.80% 3) 4-BROMOFLUOROBENZENE 24.30 174 518513 4.73 ug/L -0.12 Spiked Amount 5.000 Recovery = 94.60% 25) TOLUENE-D8 18.40 98 1678450 5.13 ug/L -0.12 Spiked Amount 5.000 Recovery = 102.60% Target Compounds Qvalue 4)•DICHLORODIFLUOROMETHANE 4.83 85 473256 12.24 ug/L 99 5) CHLOROMETHANE 5.45 50 422424 10.43 ug/L 98 6) VINYL CHLORIDE 5.57 62 234052 10.76 ug/L 97 7) BROMOMETHANE 6.54 94 239965 9.46 ug/L 95 8) CHLOROETHANE 6.68 64 238040 10.62 ug/L 94 9) TRICHLOROFLUOROMETHANE 7.23 101 454633 9.16 ug/L 99 12) ACETONE 8.21 43 89511 12.92 ug/L 96 13) 1,1-DICHLOROETHENE 8.56 61 801765 13.60 ug/L 98 14) METHYLENE CHLORIDE 9.57 49 884110 12.73 ug/L 98 15) METHYL TERT BUTYL ETHER 9.86 73 882908 11.09 ug/L 99 16) TRANS-1,2-DICHLOROETHENE 10.22 61 877211 10.98 ug/L 96 17) 1,1-DICHLOROETHANE 11.12 63 1053433 10.67 ug/L 97 18) 2-BUTANONE (MEK) 11.95 43 142431 9.60 ug/L 89 19) 2,2-DICHLOROPROPANE 12.33 77 787622 10.82 ug/L 96 20) CIS-1,2-DICHLOROETHENE 12.43 96 637873 10.50 ug/L 99 21) CHLOROFORM 12.77 83 1106394 10.67 ug/L 98 22) BROMOCHLOROMETHANE 13.14 49 518191 10.14 ug/L 98 23) 1,2-DICHLOROETHANE 14.49 62 785788 12.00 ug/L 99 26) 1,1,1-TRICHLOROETHANE 13.65 97 783727 10.81 ug/L 99 27) 1,1-DICHLOROPROPENE 13.98 75 796710 11.21 ug/L 96 28) CARBON TETRACHLORIDE 14.23 117 663896 10.91 ug/L 96 29) BENZENE 14.57 78 2144414 10.67 ug/L 99 30) TRICHLOROETHENE 15.85 95 623505 10.54 ug/L 97 31) 1,2-DICHLOROPROPANE 16.21 63 597001 10.23 ug/L 99 32) DIBROMOMETHANE 16.87 174 298370 9.74 ug/L 82 33) BROMODICHLOROMETHANE 16.72 83 820751 11.21 ug/L 97 34) 2-CHLOROETHYL VINYL ETHER 17.21 63 208659 11.28 ug/L 98 35) METHYL ISO-BUTYL KETONE 17.30 58 110601 10.63 ug/L 95 36) CIS-1,3-DICHLOROPROPENE 17.83 75 888357 11.16 ug/L 97 37) TOLUENE 18.57 91 2308914 10.45 ug/L 100 3 8) TRANS-1,3-DICHLOROPROPENE 18.85 75 652797 11.46 ug/L 97 39) 1,1,2-TRICHLOROETHANE 19.24 97 405935 10.69 ug/L 99 40) TETRACHLOROETHENE 20.02 166 591799 9.33 ug/L 98 41) 1,3-DICHLOROPROPANE 19.77 76 761442 10.94 ug/L 99 42) DIBROMOCHLOROMETHANE 20.46 129 485401 10.65 ug/L 97 43) 1,2-DIBROMOETHANE 20.91 107 410539 10.62 ug/L 100 44) CHLOROBENZENE 21.79 112 1566855 10.35 ug/L 97 45) 1,1,1,2-TETRACHLOROETHANE 21.84 131 532155 10.59 ug/L 97 46) 2-HEXANONE 19.14 43 195022 7.37 ug/L 90 47) ETHYLBENZENE 21.83 91 2726977 10.87 ug/L 98 48) P & M-XYLENE 21.98 106 1876311 20.76 ug/L 93 (#) = qualifier out of range (m) = manual integration 0306C10.D HP022702.M Wed Mar 06 10:02:20 2002 Page 1

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