DEP document fragment, February 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) K Data File : C:\HPCHEM\1\DATA\02FEB05\0205C10A.D Vial: 5 Acq On : 5 Feb 2002 9:13 pm Operator: 201-wb Sample : cal 10 Inst : GC/MS Ins Mise : February 5, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Time: Feb 13 17:02 2002 Quant Results File: HP020502.RES Quant Method : C:\HPCHEM\1\METHODS\HP020502.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Wed Feb 13 16:57:04 2002 Response via : Initial Calibration DataAcq Meth : HP020502

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZENE 15.11 114 2158424 5.00 ug/L 0.00 2 4) CHLOROBENZENE-D5 21.78 117 2114081 5.00 ug/L 0.02 52) 1,4-DICHLOROBENZENE-D4 26.95 152 1003870 5.00 ug/L 0.00 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.35 65 857508 4.59 ug/L 0.00 Spiked Amount 5.000 Recovery = 91.80% 3) 4-BROMOFLUOROBENZENE 24.35 174 815960 4.93 ug/L 0.00 Spiked Amount 5.000 Recovery = 98.60% 25) TOLUENE-D8 18.47 98 2623631 4.97 ug/L 0.00 Spiked Amount 5.000 Recovery = 99.40% Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.86 85 752321 9.15 ug/L 98 5) CHLOROMETHANE 5.49 50 559472 13.03 ug/L 100 6) VINYL CHLORIDE 5.59 62 266808 11.79 ug/L 98 7) BROMOMETHANE 6.59 94 351911 11.20 ug/L 99 8) CHLOROETHANE 6.73 64 309377 11.16 ug/L 99 9) TRICHLOROFLUOROMETHANE 7.30 101 679777 10.48 ug/L 96 10) Isopropyl Alcohol 7.85 45 3036 27.12 ug/L 77 11) 1,l,2-Trichloro-l,2,2-trif 8.19 101 471868 9.80 ug/L 97 12) ACETONE 8.27 43 167382 12.43 ug/L 96 13) 1,1-DICHLOROETHENE 8.62 61 1006711 9.93 ug/L 98 14) METHYLENE CHLORIDE 9.63 49 1109307 11.05 ug/L 98 15) METHYL TERT BUTYL ETHER 9.93 73 1172113 9.29 ug/L 94 16) TRANS-1,2-DICHLOROETHENE 10.29 61 1214745 9.88 ug/L 95 17) 1,1-DICHLOROETHANE 11.18 63 1412136 9.53 ug/L . 97 18) 2-BUTANONE (MEK) 19) 2,2-DICHLOROPROPANE 12.01 12.40 43 77 374575 1084692 14.04 ug/L— 44 8.74 ug/L 98= 2 100 20) CIS-1,2-DICHLOROETHENE 12.50 96 832609 9.39 ug/L 98 21) CHLOROFORM 12.83 83 1459012 8.84 ug/L 98 22) BROMOCHLOROMETHANE 13.22 49 694182 9.77 ug/L 98 23) 1,2-DICHLOROETHANE 14.56 62 990149 8.51 ug/L 98 26) 1,1,1-TRICHLOROETHANE 13.72 97 1143547 8.53 ug/L 98 27) 1,1-DICHLOROPROPENE 14.05 75 1156239 9.66 ug/L 99 28) CARBON TETRACHLORIDE 14.31 117 946348 8.67 ug/L 99 29) BENZENE 14.64 78 2829641 9.59 ug/L 98 30) TRICHLOROETHENE 15.93 95 886937 9.04 ug/L 97 31) 1,2-DICHLOROPROPANE 16.28 63 820746 9.53 ug/L 98 32) DIBROMOMETHANE 16.96 174 399986 8.69 ug/L 94 33) BROMODICHLOROMETHANE 16.80 83 1052059 8.11 ug/L 99 (#) = qualifier out of range (m) = manual integration 0205C10A.D HP020502.M Wed Feb 13 17:02:50 2002 Page 1

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