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GC/MS analysis results for sample AD30705, Jan 28 2002

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Laboratory report documenting gas chromatography mass spectrometry results for sample AD30705 conducted on January 28, 2002.

NYC-WTC_000018605–000018623

Folder label: “GCMS X 12/19/01 A 1/2/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C: \HPCHEM\ 1 \DATA\DEC3101\30705.D Vial: 46 Acq On 2 Jan 2002 9:30 am Operator: 209 GALOS Sample gems scan 12/19a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 11 3-1sopropoxy-1,1,1,7,7,7-hexam Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 31.71 0.49 ug/1 97225 Chrysene-dl2 33.02 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 3-Isopropoxy-1,1,1,7,7,7-hexamethyl 576 C18H5207Si7 071579-69-6 32 2 Mercaptoacetic acid, bis(trimethyls 236 C8H20O2SSi2 006398-62-5 22 3 Silanamine, N-[2,6-dimethyl-4-[(tri 281 C14H27NOSi2 072088-09-6 11 4 Methyl bis (p-chlorgiphenyl) acetate 294 C15H12C12O2 005359-38-6 10 Abundance Scan/2905 (31.710 min): 30705.D (-) m/ z 73.00 100.00% 73

5000 147 221 t--- 12" f 38 —H 117 ’I i " " j 7611246 211,325 355... f T "0" j"rf II i i-i f ।-j i i j । i 429 31.40 31.60 31.80 32.00 m/z 147.10 35.63% miz-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #60503:3-Isopropoxy-1,1,1,7,7,7-hexamethyl-3,5,5-tris(trim 73

5000 T / \ T 7 147 31.40 31.60 31.80 32.00 m/z 221.05 22.21% . 415, .519561 miz-> ' 5o' ' 100 ' 150 ‘ ' 200 250 ‘ ‘ 300 ' 350 ' ‘ 400 450 500 550 ' Abundance #30949: Mercaptoace tic acid, bis(trimethylsilyl)- 73 147 31.40 31.60 31.80 32.00 5000 m/z 234.95 19.27% 221 45 104. I 193 ■ 'I ir miz-> 50 100 150 200 250 300 350 400 450 500 550 ‘ Abundance #39584: Silanamine, N-[2,6-dimethyl-4-[(trimethylsilyl)oxy] —■ 1 ■ i ■ • ■ ■ i 1 • • ' 1 1 1 1 1 i 1 1 1 1 I 73 31.40 31.60 31.80 32.00 281 m/z 236.95 12.54% 209 5000 45 251 . 179

■ ■ i ■ ■ —120lane 147 I 1 ■ i • ' 1 ■ i ■ ■ ■ ■ i 1 ' ■ ■ i 1 ' • ‘ i ' • ‘ ■ i ■ • ' ■ i ■ ■ ■ • i ‘ 1 ' ■ i ■ 1 ' • i ■ ■ ■ ■ i miz-> 50 100 150 200 250 300 350 400 450 500 550 31.40 31.60 31.80 32.00

30705.D GCMS1126.M Fri Jan 25 11:27:43 2002 Page 11

NYC-WTC_000018622

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NYC-WTC_000018622Source: NYC Law Department, mirrored locally

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