GC/MS calibration data for sample 30647, Dec 2001

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Library Search Compound Report

Data File : M:\INSTRU~1\209\DATA\DEC2101\30647.D Vial: 64 Acq On : 24 Dec 2001 6:34 am Operator: 209 GALOS Sample : gc/ms scan 12/18 Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Propanone, 1,1,1-trichloro- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

7.72 0.56 ug/1 94458 1,4-Dichlorobenzene-d4 11.67

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Prppanone, 1,1,1-trichloro- 160 C3H3C130 000918-00-3 33 2 2-Acetyl-l,4,5,6-tetrahydropyridine 125 C7H11NO 000000-00-0 7 3 2-Acetylthiazole 127 C5H5NOS . 024295-03-2 4 4 Acetoacetic acid, 1-isopropylcycloh 226 C13H2203 015780-57-1 4 Abundance Scan 291 (7.719 min): 30647.D (-) m/z 43.00 100.00%

y 43

5000 PrrTfrr 4144821** ′ I TTT 7.40 7.60 7.80 8.00 1 m/z-> 10 37 ImPPt 20 30 40 +4,55 60163 6970 50 Q ’ * ’ 'T 80 97193 .... 119 177 , 90 100 110 120 130 m/z 81.85 10.62% Abundance #12247:2-Propanone, 1,1,1-trichloro- 43

5000 ■ ■ । ■ ■ ■ ■ । 11 ■ ■ ■ ■ । • • • ■ । 7.40 7.60 7.80 8.00 15 m/z 126.9.0 9.80% I 35 49 ____ 85 97 117 125 m/z-> ■ • i ■ ■1 ■ i •1 • ■ i ■ • ■ • i • 10 20 30 40 ' sb “eo" 70 '' 80 " 90 ' -too'' 110 120 130 Abundance #4332: 2-Acety-1.4.5,6-tetrahydropyridine 43 54 82 • • ' i ■ • • * i • • ■ ’ i * ' ‘ • i • • • • k 7.40 7.60 7.80 8.00 5000 125 m/z 82.95 8.21% i;

110 97 T19BTmumRmmOmBOTuor miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #4717:2-Acetylthlazole ■ ■ • । ■ ■ ■ ■ । ■ • • ■ । • i ■ ■1 ■ i 43 7.40 7.60 7.80 8.00 m/z 124.95 8.02% 5000 99 58 127 112 , 85 33 1 ‘ ' I • ‘ ‘ ' I ‘ ‘ ‘ ' I ' ' ‘ ' I ' ' ‘ ' I ' ' II,... ......Il.... 1 ' I ‘ ‘ ‘ ' I ■ ' I ■ ■ ■ ■ i ■ ■ •' i '' ■ (i ■ ■ • ■ i ‘ ■ i m/z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 7.40 7.60 7.80 8.00

30647.D GCMS1126.M Fri Feb 01 14:46:04 2002 Page 2

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