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GCMS analysis results for sample AD30985, Jan 2002

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Laboratory report documenting GCMS analysis of sample AD30985 conducted on January 25, 2002.

NYC-WTC_000018262–000018285

Folder label: “GCMS X 12/27/01 A 1/16/02

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\HPCHEM\1\DATA\DEC3101\30985.D Vial: 39 Acq On 2 Jan 2002 1:45 am Operator: 209 GALOS Sample gems scan 12/19 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 7 Benzoic acid, 4-ethoxy-, ethyl Concentration Rank 13 R.T. EstConc Area Relative to ISTD R.T. 21.06 1.32 ug/1 489196 Acenaphthene-dl0 20.56 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Benzoic acid, 4-ethoxy-, ethyl este 194 C11H1403 023676-09-7 96 2 Benzoic acid, ethoxy-, ethyl ester 194 C11H14O3; 075333-22-1 43 3 Ethanone, 1 - (4 - ethoxyphenyl) - 164 C10H12O21 001676-63-7 42 4 Ethylparaben 166 C9H10O3 000120-47-8 38 Abundance Scan 1745 (21.062 min): 30985.D (-) m/z 120.95 100.00% 121

5000 149 138 194 65 39 93 166 20.80 21.00 21.20 21.40 miz-> ---++85l 50 —.TT 109 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 m/z 149.00 " i'1 47.69% Abundance #69400: Benzoic acid, 4-ethoxy-, ethyl ester 121

149 5000 194 138 20.80 21.00 21.20 21.40 65 93 166 m/z 194.05 31.24% .... 50. ) 75.... .............. TTTTTMTTT T’"’I1—B—-T8B332"38107""T9T •■i■■ miz-> :20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance> #21246: Benzoic acid, ethoxy-, ethyl ester 121

20.80 21.00 21.20 21.40 138 m/z 138.0 27.02% 5000 194 29 65 149 ! 39 93 1 166 miz->20 ' 30 ' 40 ' 50 "ad 70" 80 ‘ 90 100 110 120 130 140 150 160 170 180 190 200 Abundance' #13415: Ethanone, 1-(4-ethoxypheny!)- 121 20.80 21.00 21.20 21.40 149 m/z 64.95 21.04% 5000 93 164 65 27 — — miz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 20.80 21'00 21.20 2140

30985.D GCMS1126.M Wed Jan 23 08:57:30 2002 Page 7

NYC-WTC_000018275

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NYC-WTC_000018275Source: NYC Law Department, mirrored locally

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