GCMS analysis results for sample AD30473, Jan 2002

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Data File : C:\HPCHEM\1\DATA\DEC3101\30473.D Vial: 14 Acq On : 31 Dec 2001 11:37 pm Operator: 209 GALOS Sample : gems scan 12/14fb Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Naphthalene-d8- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

15.27 18.14 ug/1 6307100 Acenaphthene-dl 0 20.56

Hit# of 5 Tentative ID MW MolForm CAS# Qual l Naphthalene-d8- 136 C10D8 001146-65-2 97 2 1-(3-Methyl-2-pyrazinyl)-1-ethanone 136 C7H8N20 000000-00-0 59 3 Allopurinol 136 C5H4N40 000315-30-0 40 4 Benzamide, 3-amino­ 136 C7H8N2O 003544-24-9 36 Abundance Scan 1114 (15.275 min): 30473.D (-) m/z 136.(^ 100.00% 136

5000

54 68 . 108 15.00 15.20 15.40 15.60 1 i? 0- ,,,, 36 421 ,, ,?.i I,,, । Y 90.,119%.11.,.. 1181241391 1— m/z 137.0 10.82% m/z~> 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #6596: Naphthalene-d8- 136

5000 15.00 15.20 15.40 15.60 108 m/z 108.10 10.65% 54* 66 76 82 an ■ ■ । । । । > । • । • > । ■ -P I ■ ■ ।1 I i ■ ‘ ■ i ' ■ m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #6433 1-(3-Methyl-2-pyrazinyl)-1-ethanone 136 ■ ■ i ■ ■ • ■ i ' • ■ 1 i 1 ■ > • । > 15.00 15.20 15.40 15.60 5000 94 m/z 54.00 10.18%

42 52 67 108 121 , I m/z-> Abundance 30 • ' I 1 ■ 1 ‘ r TTr I | ri I ■ I I I ri | II > 1 | I ■ II | 40 50 60 70 80 90 100 #6376: Allopurinol ■•i 1 • ■ ' i ' 1 1 'I1■1 ■ i ' 1 1 4 i ■ ■ 110 120 130

136 140 A15.00 15.20 15.40 15.60 TFttI

m/z 134.00 9.09% 5000 52 38 ,

m/z—> -l 30 40 50 60 67 70 80 94 109 • • i ■ ‘ • 11 > • • ■ l • • ■ ■ । ■1 • • । • ■ ■ ■ । 80 90 100 110 120 ■ i ■ ■ ■ ■ । 120 130 ■ 1

140 15.00 15.20 15.40 15.60

30473.D GCMS1126.M Wed Jan 16 08:24:56 2002 Page 3

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