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GCMS analysis results for sample AD30633, Jan 2002

Machine-extracted title · confidence 95%

Laboratory report documenting GCMS analysis of sample AD30633 including DDD surrogates on January 22, 2002.

NYC-WTC_000017210–000017232

Folder label: “GCMS X 12/17/01 A 12/28/01 1/3/01 1/4/01

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : M:\INSTRU~1\209\DATA\DEC2701\30633.D Vial: 27 Acq On : 28 Dec 2001 3:23 pm Operator: 209 GALOS Sample : GC/MS SCAN 12/17 Inst : GC/MS 209 Mise ’ Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 15 1,1,1,5,7,7,7-Heptamethyl-3,3- Concentration Rank 13

R.T. EstConc Area Relative to ISTD R.T.

36.72 0.58 ug/1 ■114100 Perylene-dl2 37.12

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,1,1,5,7,7,7-Heptamethyl-3,3-bis(t 444 C13H40O5Si6 038147-00-1 36 2 Trisiloxane, 1,1,1,5,5,5-hexamethyl 384 C12H3604Si5 003555-47-3 32 3 l-Monolinoleoylglycerol trimethylsi 498 C27H5404S12 054284-45-6 28 4 Mercaptcacetic acid, bis(trimethyls 236 C8H20O2SSi2 006398-62-5 23 Abundance Scan 3450 (36.719 mtn): 30633.D (-) m/z 73.00 1 00.00% 73 ■ 147 5000 221 281 355 ■ * i ■ ■ ' ■ i • • ■ 4 i'1"1'1 1 i ‘ 1 ' 1 1 36.40 36.60 36.80 37.00 45. . 103 ( . 193 ; . .i, ■> . • • • 1*I* 429 - 327,, _ m/z 147.0,0 63.08% m/z-> 50 100 150 200 250 300 350 400 450

.. i.. Abundance #56714:1,1,1,5,7,7,7-Heptamethyl-3,3-bis(trimethylsiloxy)t 73

147 5000 267 355 429 36.40 36.60 36.80 37.00 45 207 ..................... ...... 38.01% * * * i • i ■ 1 ' i • ■ • ' i ■ ■ ' ■ i • • miz-> 50 100 150 200 250 300 350 400 450 Abundance #74103: Trisiloxane, 1.1,1,5.5,5-hexamethyl-3,3-bis[(trimet 73 147 L 36.40 36.60 36.80 37.00 A ‘ • r

5000 m/z 280.95 19.68% 281 45 369 • .50 ' 1. 100 117 4 207, . ................... . ................. m/z-? 150 200 250 300 ' ' 350 400 450 wwwwl W Abundance #58871:1-MonoIinoleoylglycerol trimethylsilyl ether ' * I * ‘ J * I * ‘ 1 1 1 ‘ ‘ 1 ‘ ‘ ‘ ‘ 1 1 73 36.40 36.60 36.80 37.00 m/z 207.05 18.75% 5000 147 207 -/ "Wwd 34 103 281 ‘ ‘ | ■ ■ ■ • | • • < • । ■ t ■ ■ . > । 1 ■ .......... 395............ 482 300/’* 350 ‘ 400 ' ‘ 450‘ ‘ ‘ ‘ TIdBnmmn—mnnn m/z—> 50 100 150 200 250 36.40 36.60 36.80 37.00

30633.D GCMS0103.M Thu Jan 10 15:24:54 2002 Page 15

NYC-WTC_000017231

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NYC-WTC_000017231Source: NYC Law Department, mirrored locally

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