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GCMS unknowns analysis report for sample AD30424, Jan 2002

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Laboratory analysis report from the DEP identifying unknown compounds in environmental sample AD30424 using GCMS on January 18, 2002.

NYC-WTC_000017079–000017087

Folder label: “GCMS X 12/14/01 A 1/1/02

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NYC 9/11 Public Portal Document : Quantitation Report (QT Reviewed) r Data File : C:\HPCHEM\1\DATA\DEC3101\30424.D Vial: 23 Acg On : 1 Jan 2002 8:19 am Operator: 209 GALOS Sample : gems scan 12/i4a Inst : GC/MS 209 Misc : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Jan 1 9:08 2002 Quant Results File: GCMS1126.RES Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update +: Fri Dec 28 15:11:00 2001 Response via : Initial Calibration DataAcg Meth : GCMS1126 Internal Standards R.T. QIon Response Conc Units Dev (Min) 1) 1,4-Dichlorobenzene-d4 11.68 152 680989 20.00 ug/l -0.02 10) Naphthalene-ds 15.28 136 2604331 20.00 ug/l -0.03 17) Acenaphthene-d10 20.56 164 1360601 20.00 ug/l -0.01 29) Phenanthrene-d10 24.99 188 1893527 20.00 ug/l 0.00 38) Chrysene-d12 33.02 240 1121603 20.00 ug/l -0.01 44) Perylene-di2 37.13 264 601738 20.00 ug/l 0.00 System Monitoring Compounds 37) 2,4-DDD 30.07 235 110655 5.32 ug/ml 0.00 Spiked Amount 5.000 Recovery = 106.40% Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.16 74 372 N.D. 3) bis (2-Chloroethyl) ether 0.00 93 0 N.D. 4) 1,3-Dichlorobenzene 0.00 146 0 N.D. 5) 1,4-Dichlorobenzene 0.00 146 C) N.D. 6) 1,2-Dichlorobenzene 0.00 146 C) N.D. 7) 2,2'-oxybis(1-Chloropropan 0.00 45 0 N.D. 8) N-Nitroso-di-n-propylamine 0.00 70 C) N.D. 9) Hexachloroethane 0.00 117 0 N.D. 11) Nitrobenzene 0.00 77 0 N.D. 12) Isophorone 0.00 82 0 N.D. 13) bis(2-Chloroethoxy)methane 0.00 93 0 N.D. 14) 1,2,4-Trichlorobenzene 0.00 180 0 N.D. 15) Naphthalene 15.34 128 665 N.D. 16) Hexachlorobutadiene 0.00 225 0) N.D. 18) Hexachlorocyclopentadiene 0.00 237 0 N.D. 19) 2-Chloronaphthalene 0.00 162 0 N.D. 20) Dimethylphthalate 0.00 163 C) N.D. 21) 2,6-Dinitrotoluene 0.00 165 0 N.D. 22) Acenaphthylene 0.00 152 0 N.D. 23) Acenaphthene 0.00 153 0 N.D. 24) 2,4-Dinitrotoluene 21.11 165 192 N.D. 25) Diethylphthalate 0.00 149 ° N.D. 26) 4-Chlorophenyl-phenylether 0.00 204 0 N.D. 27) Fluorene 0.00 166 0 N.D. 28) Azobenzen/ 1,2-Diphenylhyd 0.00 77 0) ‘N.D. (#) = qualifier out of range (m) = manual integration 30424.D GCMS0103.M Tue Jan 15 14:38:58 2002 Page 1 NYC-WTC_000017081

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NYC-WTC_000017081Source: NYC Law Department, mirrored locally

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