GCMS reference analysis for nitrosamines and chlorobenzenes, Jan 2002

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Quantitation Report (QT ‘Reviewed) Data File : C:\HPCHEM\l\DATA\DEC1901\REFA.D Vial: 16 Acq On : 20 Dec 2001 4:06 pm Operator: 209 GALOS Sample : gc/ms scan 12/12 a Inst : GC/MS 209 Mise : Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Dec 20 16:55 2001 Quant < Results File: GCMS1126.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Dec 14 12:19:30 2001 Response via : Initial Calibration DataAcq Meth : GCMS1126

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 11.67 152 938395 20.00 ug/1 -0.03 10) Naphthalene-d8 15.28 136 3587106 20.00 ug/1 -0.03 17) Acenaphthene-diO 20.56 164 1773107 20.00 ug/1 -0.02 29) Phenanthrene-diO 24.97 188 2612629 20.00 ug/1 -0.02 38) Chrysene-dl2 33.01 240 1737994 20.00 ug/1 -0.02 44) Perylene-dl2 37.11 264 1146647 20.00 ug/1 0.00

System Monitoring Compounds 37) 2,4-DDD 30.06 235 137068 3.62 ug/mL -0.01 Spiked Amount 5.000 Recovery = 72.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.41 74 95170 2.31 ug/1 81 3) bis(2-Chloroethyl)ether 11.10 93 217928 3.36 ug/1 93 4) 1,3-Dichlorobenzene 11.58 146 141950 2.08 ug/1 98 5) 1,4-Dichlorobenzene 11.58 146 141950 2.06 ug/1 99 6) 1,2-Dichlorobenzene 12.23 146 156926 2.47 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 12.57 45 353794 4.29 ug/1 # 92 8) N-Nitroso-di-n-propylamine 12.96 70 152620 4.14 ug/1 90 9) Hexachloroethane 13.07 117 44256 1.76 ug/1 95 11) Nitrobenzene 13.36 77 188464 3.37 ug/1 89 12) 1sophorone 14.00 82 442005 4.10 ug/1 94 13) bis(2-Chloroethoxy)methane 14.69 93 256883 3.55 ug/1 99 14) 1,2,4-Trichlorobenzene 15.17 180 125362 2.41 ug/1 96 15) Naphthalene 15.33 128 545406 3.18 ug/1 100 16) Hexachlorobutadiene 15.88 225 44916 1.77 ug/1 95 18) Hexachlorocyclopentadiene 18.08 237 197 N.D. 19) 2-Chioronaphthalene 18.83 162 299762 2.96 ug/1 97 20) Dimethylphthalate 19.93 163 433767 3.68 ug/1 100 21) 2,6-Dinitrotoluene 20.15 165 66919 2.40 ug/1 # 61 22) Acenaphthylene 20.09 152 469803 3.30 ug/1 100 2 3) Acenaphthene 20.65 153 348969 3.43 ug/1 100 24) 2,4-Dinitrotoluene 21.33 165 74961 2.12 ug/1 # 75 25) Diethylphthalate 22.06 149 443230 4.06 ug/1 98 26) 4-Chioropheny1-phenylether 22.20 204 165465 3.48 ug/1 95 27) Fluorene 22.16 166 371232 3.56 ug/1 97 28) Azobenzen/ 1,2-Diphenylhyd 22.66 77 397586 3.53 ug/L # 89

(#) = qualifier out of range (m) = manual integration REFA.D GCMS1126.M Mon Dec 31 12:25:28 2001 Page 1

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