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GCMS calibration results, June 11 2002

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Calibration verification data for volatile organic compound analysis using gas chromatography-mass spectrometry on June 11, 2002.

NYC-WTC_000015679–000015682

Folder label: “GCMS X 6/7/02 A 6/10/02

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NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed) Data File : C:\MSDCHEM\1\DATA\0610022\CAL2.D Vial: 6 Acq On : 10 Jun 2002 3:06 pm Operator: Sample : calibration 20 Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Jun 11 08:14:09 2002 Quant Results File: 060302.RES Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Last Update : Mon Jun 10 11:43:55 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN

Compound R.T. Qlon Response Cone Unit Qvalue 36) Fluoroanthene 26.49 202 7104602 17.48 ug/L 100 3 8) Pyrene 27.12 202 6731306 16.59 ug/L 99 39) Butylbenzylphthalate 29.48 149 1495409 15.84 ug/L 97 40) Benzo(a)anthracene 30.74 228 4280100 14.97 ug/L 99 41) Bis(2-ethylhexyl)phthalate 31.34 149 1590828 16.18 ug/L 100 42) Chrysene 30.82 228 5273855m 17.36 ug/L 44) Di-n-octylphthalate 33.18 149 1340376m 17.51 ug/L 45) Benzo(b)fluoranthene 33.70 252 2693091 13.14 ug/L 99 46) Benzo(k)fluoranthene 33.77 252 4597200 18.68 ug/L 99 47) Benzo(a)pyrene 34.50 252 2894866m 14.89 ug/L 48) Indeno(1,2,3-cd)pyrene 37.32 276 959603m 7.26 g/L 49) Dibenz(a,h)anthracene 37.43 278 1575798m 10.86 ug/L 50) Benzo(g,h,i)perylene 38.05 276 2240969m ■±4146 ug/L

(#) = qualifier out of range (m) = manual integration (+) = signals summed CAL2.D 060302.M Tue Jun 11 09:22:53 2002 Page 2

NYC-WTC_0000 15681

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NYC-WTC_000015681Source: NYC Law Department, mirrored locally

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