GCMS reference standard results, June 10 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\060602\12743 .D Vial: 6 Acq On 6 Jun 2002 3:22 pm Operator: McLean Sample 6/3 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator). Title : 508 Modified GC/MS scan 16 Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 15 Nitrosyl chloride Concentration Rank 17 R.T. EstConc Area Relative to ISTD R.T.

4.95 0.33 ug/L 233689 1,4-dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Nitrosyl chloride 65 CINO 002696-92-6 2 2 2-Propenoyl chloride 90 C3H3C1O 000814-68-6/2 3 Propanoyl chloride 92 C3H5C1O 000079-03-/ 2 4 Difluorine monoxide 54 F2O 007783-41/7 1 Abundance Scan 319 (4.953 min): 12743.D (-316) (-) m/ z 35.10 100.00% 35 WwMw AWw MWWAh ilk 5000 86 47 1 ■ ■ i ■ ■ ■ ■ 1 1 1 1 ' 1 1 1 1 1 I — 4.60 4.80 5.00 5.20 5.40 0- ■ ' i ' ■ ■ ■ i ■ ■ 1 ' i ■ ■ ■ ■ i ■ ■ m/z 86.00 45.50% miz-> 0 10 20 30 40 50 60 70 80 90 100 Abundance #713: Nitrosyl chloride 30

5000 460 4.80 5.00 5.20 5.40 35 m/z 47.00 14.83% "... 14 0- ■ • i ■ • • ' I 1 1 1 1 1 1 1 1 ' 1' 1 ■ ■ i ■ ■ 1 • i 1 ' ■ ■ i ‘ • 1 ■ i ' ■ • ■ i ■ 1 ■ ■ i ■ 1 ' ■ i ■ m/z-> 0 10 20 30I 40 50 60 70 80 90 100 Abundance #60:2-Propenoyl chloride 27 55 ■ ■ i ■ ■ ■ ■ i • ■ ■ • i 1 1 1 1 1 1 1 ' 1 1 1 4.60 4.80 5.00 5.20 5.40 5000 m/ z 43.10 12.33%

#— 3740,45,50, +1,67 72.77,83 —H 90 niz-> 01 1101 0 10 419./ 20 30 40 50 60 70 80 90 100 Abundance #472: Propanoyl chloride 29 460 4.80 5.00 5.20 5.40 57 m/z 87.10 12.15% 5000 < 44 2 14 24, 35 42 49 , 65 71 76 82 91 0J T-PI ' ■1 1 ' 1 । । -i-i । ■ 1'1 119n/mmBBOm — • ■ i ■ ■ ■ i ■ * n/z-> 0 10 20 30 40 50 60 70 80 90 100 | 4.60 4.80 5.00 5.20 5.40

12743.D 060302.M Mon Jun 10 10:22:06 2002 Page 18

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