GCMS reference standard results, June 10 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C : \MSDCHEM\ 1 \DATA\ 06060212743.D Vial: 6 Acq On 6 Jun 2002 3:22 pm Operator: McLean Sample 6/3 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan ’5 Library : C: \DATABASE\NIST98 . L ********************************************************************* Peak Number 14 Ethyl Chloride Concentration Rank 14 R.T. EstConc Area Relative to ISTD R.T.

4.66 0.43 ug/L 307983 1,4-dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qua

1 Ethyl Chloride 64 C2H5C1 000075-00-3/4 2 Borane, trifluoro- 68 BF3 007637-07-2 2 3 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7 2 4 Ethanol, 2,2-dichloro- 114 C2H4C120 000598-38-9 1 Abundance l Scan 270 (4.666 min): 12743.D (-268) (-) m/z 49.10 100.00% 49

5000

41 83 4.40 4.60 4.80 5.00 0' . |hh । -rp 1 ' I ■ ■' ■ 1111 11 1 |l''' * * 111 । ■ 11 11 m/z 51.10 29.98% iz—> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #107943: Ethyl Chloride 23

64 5000 4.40 4.60 4.80 5.00 49 m/z 48.00 19.60% 35 0-- 15 I ur ' ■ II/, ■' nMIl ■ i ■ ■ • ■ i ■ ■ ■ ■ i ■ ‘ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ • ■ ■ i ■' niz-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12321: Borane, trifluoro- 49

4.40 4,60 4.80 5.00 5000 m/z 51.90 15.89%

11 19 30 38 68 0-TTT—mPmmm i * ■ ■ ' I ■ ■ ■ 11 ■ ■ ■ ■ i ■ ■ ■ ■ i1 ■ 1 ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ • ■ i11 miz-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #1099: Boron trifluoride etherate 31 4.40 4.60 4.80 5.00 m/z 82.90 13.98% 59 5000- 45 74 "WMMWAWWnAWAKt, 0- ■ ■ ।1 15. 25 66 tr THTT 81 93 127 ■ ‘ i ' ' ■ ' i ■ ■ ■ • i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ' ' ■ i ' ■ m/z—> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 4.40 4.60 4.80 5.00

12743.D 060302.M Mon Jun 10 10:22:03 2002 Page 17

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