GCMS reference standard results, June 10 2002

NYC 9/11 Public Portal Document Library searen compound Report

Data File C:\MSDCHEM\1\DATA\060602\12743.D Vial: 6 Acq On 6 Jun 2002 3:22 pm Operator: McLean Sample 6/3 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan '5 Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 16 2-Butenoic acid, (E)- Concentration Rank 16 R.T. EstConc Area Relative to ISTD R.T.

4.98 0.40 ug/L 288224 1,4-dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qua

1 2-Butenoic acid, (E) - 86 C4H602 000107-93-7/7 2 Azetidine, 1-nitroso- 86 C3H6N20 015216-10-1 7 3 Crotonic acid 86 C4H602 003724-65-0 7 4 Ethenamine, N-methyl-N-nitroso- 86 C3H6N20 004549-40-0 4 Abundance Scan 324 (4.983 min): 12743.D (-322) (-) m/z 86.00 /100.00% 85

5000

38 ■ i ■ 1 ■ ' i ' 1 1 1 1 1 1 1 ' I ' 1 35 11 42 4750 4.60 4.80 5.00 5.20 5.40 0 100g ”’l111111 ■ 1 ■ i ■ ■ ■ ■ i ■1 m/Z 84.00 52.01% n/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #34651:2-Butenoic acid, (E)- 85 41

5000- ' i ■ ■ ■ ■ i ■ ■ ■ ■ i ' ' 1 ' i 1 ' ■ ■ i ' 1 69 4.60 4.80 5.00 5.20 5.40 45 m/z 38.00 14.03% 27 38

miz-> 0 TUt — 24143134 H—TTTI 7982 1 489—m 5053 5760 66 72 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #734: Azetidine, 1-nitroso- 39

4.60 4.80 5.00 5.20 5.40 41 5000 86 m/ Z 86.80 13.79% 44 55 । 69

n/z-> 0- 11 ■ " i ■ " ' i " 15 20 25 30 1 thH35 35 40 4++ 52

45 50 55 60 65 70 | MH | , I I । | I ... | 1 ... | .... |

75 80 85 90 *Tpi ■ ■■ i ■ ■ 95 ’"4 h Abundance #116767: Crotonic acid T—I 86 4.60 4.80 5.00 5.20 5.40 41 5000 69 27 38 45 58

m/z-> 0 -4 +4 5053 ,| 66 72 TTI III| 89——— ■' I ■'1 ‘'11' I ■ ■' ■ l ■■ 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 l '■ ■ ■ I'' .... 4.60 4.80 5.00 5.20 5.40

12743.D 060302.M Mon Jun 10 10:22:08 2002 Page 19

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