GCMS reference standard results, June 10 2002

NYC 9/11 Public Portal Document LIbrary searen compound. Report Data File C:\MSDCHEM\1\DATA\060602\12743.D Vial: 6 Acq On 6 Jun 2002 3:22 pm Operator: McLean Sample 6/3 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan '= Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 17 Methane, chlorotrinitro- Concentration Rank 15 R.T. EstConc Area Relative to ISTD R.T. 5.37 0.41 ug/L 294141 1,4-dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Methane, chlorotrinitro- 185 CC1N306 001943-16-4 /2 2 Nitrosyl chloride 65 CINO 002696-92-/ 2 3 Ethanethiol, 2-amino-, hydrochlo... 113 C2H8C1NS 000156-57/0 1 4 Ethyl Chloride 64 C2H5C1 000075-00-3 1 Abundance Scan 390 (5.371 min): 12743.D (-386) (-) m/z 35.10 100.00% 35 4 5000 "MWhdnckpu Mw 51 86 209 ■ i ■ ■ ■ ' i 5.00 5.20 5.40 5.60 5.80

m/z-> 0- 1*1** 20 MJ 40 60 80 100 120 140 160 180 200 m/z 51.00 37.27% Abundance 35 #1181: Methane, chlorotrinitro-

139 ""aoupk 46 5000 500 5.20 5.40 5.60 5.80 93 m/z 86.00 17.71% 61 . 104 | 150 mfe-> 0- ‘ ' I ' ‘ 20 ‘ I ‘ ‘ ' * 40 60 —1001 120 * 1 1 ’I 1 80 140 160 180 200 Abundance #713: Nitrosyl chloride 33

5.00 5.20 5.40 5.60 5.80 5000 m/z 209.00 14.72%

14 I 49 0- TT • • i ■■ i ■ • • ■ i • ■ ■ ■ i 1 1 1 i ' 1 1 1 r1 1 1 1 i 1 1 ■ । 1 1 1 1 i ' 1 miz-> 20 40 60 80 100 120 140 160 180 200 Abundance #715: Ethanethiol, 2-amino-, hydrochloride • i • ■ ‘ ■ i ■ 1 ' ■ i 1 1 ‘ ■ 1 1 ■ ■ • l ■ 33 5.00 5.20 5.40 5.60 5.80 m/z 49.10 11.95%

5000

42 59 15 77

miz-> 0- | " > 1"* 20 "" , ,h * 40 60 80 100 120 140 160 180 200 5.00 5.20 5.40 5.60 5.80

12743.D 060302.M Mon Jun 10 10:22:09 2002 Page 20

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