GCMS reference standard results, June 10 2002

NYC 9/11 Public Portal Document Llbrary tsearcn compound keport

Data File C:\MSDCHEM\l\DATA\060602\12743.D Vial: 6 Acq On 6 Jun 2002 3:22 pm Operator: McLean Sample 6/3 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 12 1,2,3-Butatriene, 1-chloro­ Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T. 4.52 1.75 ug/L 1250870 1,4-dichlorob'enzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 1,2,3-Butatriene, 1-chloro- 86 C4H3C1 020658-21-3 A3 2 Ethyl Chloride 64 C2H5C1 000075-00-39 3 2-Butyne-1,4-diol. diformate 142 C6H604 036677-73-3 9 4 Chlorine oxide (C120) 86 C120 007791-21-1 5 Abundance Scan 245 (4.519 min): 12743.D (-243) (-) m/z 57.10 100.00% 51 57 88 5000 39 101 A A A ■ • ‘i 1 ■ • ■ i ■ ■ ■ ■ I1 1+II’’III 4.20 4.40 4.60 4.80 - 1 i■■■■i' ■ ■ • i ■ 1 ' 11 ■ ■ ■ ■ i' ■ 0! I 1 11 ‘i • ' ■ ■ i ■ • ' ■ i ■ ■ m/z 51.10 80.66% z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12404:1,2,3-Butatriene, 1-chloro- 51 86

5000 4.20 4.40 4.60 4.80 m/z 88.00 57.75%

miz-> Abundance Ot '' i ■ ■ ■ ■ i • ■ ' 1 i ■ ■ ■ ■ i ■ ■ 10 20 30 40 , 60___________ , —PPm 50 60 70 80 #107943: Ethyl Chloride 90 I ■ ‘ ■ ■ i ■ ■ ■ ■ i • ■ ■ 1 I ■ ■ 1 ■ i • 1 100 110 120 130 "MA.A.., 23 ■' ■ । • i ■ ■ ‘ ■ i 11 1 1 । 111 1 i 4.20 4.40 4.60 4.80 64 5000 m/z 86.00 48.34% 49 35 15 I niz-> O+ Mg ) 4 1 ' ' ' Ml *1+4441 4**114+* 1+4441+14/1+4’41+ 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #381:2-Butyne-1,4-diol, diformate 29 39 4.20 4.40 4.60 4.80 m/z 49.10 40.26%

5000 51

68

n/z-> 0 — 10 20 30 ■ 40 ibM 50 60 —— 1 ,n.। 76 70 80 86 97 113 i25 90 100 110 120 130 111u’ ’!111’111*17001Iu——III——IT-T ips ■' । 4.20 ■ i ■ ■ • ■ । 4.40 4.60 ■ i ■ ■ ■ ■ । 4.80

12743.D 060302.M Mon Jun 10 10:21:59 2002 Page 15

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