GCMS analysis results for unknown compounds, June 2002

NYC 9/11 Public Portal Document ULNLCL X DEdLCI tompoun KCpOL L

Data File C:\MSDCHEM\1\DATA\060702\12742.D Vial: 16 Acq On 7 Jun 2002 8:47 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 7 3-Butenamide Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T.

3.96 3.72 ug/L 2447450 1,4-dichlorobenzene-d4 9.89

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3 - But enami de 85 C4H7NO 028446-58-4 4 2 Propanenitrile, 3-(methylamino)- 84 C4H8N2 000693-05-0/3 3 Propiolonitrile 51 C3HN 001070-71-9 3 4 2-Chloroethanol 80 C2H5C10 000107-07-3 2 Abundance Scan 149 (3.955 min): 12742.D (-148) (-) m/z .49.10 0.00% 49 84

44 5000 87 37 40 360 3.80 4.00 4.20 4.40 01 ‘ ■ I' ■ ■ ■ I I m/z ,51.00 98.28% ■ I ““ I ‘“ I''' ‘ I“ "T1" 111 ■ • ■ I • > • ■ I ‘ ‘ ‘ ‘ 11'' ‘ 1 " ' ‘ I ‘ ‘ ‘ ‘ 1 • ‘ ‘ I ‘‘ ‘ I ‘ mfe-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #10560:3-Butenamide 44

5000 39 360 3.80 4.00 4.20 4.40 85 m/z .84.00 96.55% 97

n/z-> Of --++23,1,3033361 , 4952 5659 64 68 79 TTpp 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 j i. 11 (> > 11 j i,, 11 > ■ ri j i iH-ii i-i j । > ■ < 111 > ।

Abundance #10470: Propanenitrile, 3-(methylamino)- 44

360 3.80 4.00 4.20 4.40 50001 m/z 85.00 82.76% 28 52 1518 25 31 3740 , Ot —HH 8184 67 —mmTBBu TIKuu miz-> 5 W 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12371: Propiolonitrile ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ • ■ I 1 • ■ ‘ i ■ 51 3.60 3.80 4.00 4.20 4.40 " Z 44.10 51.72% 5000

18 228 32 ,38... 47 miz-> 0 5 12 111 ■ > 1111111111 ■ 111m।11111111..1111111

10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 i>■ i• • • <j• *■'i*“•i■*“i■■■■i* *1 *i““ J1>* j' 3.60 3.80 4.00 4.20 4.40

12742.D 060302.M Mon Jun 10 11:26:32 2002 Page 10

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