GCMS analysis results for unknown compounds, June 2002

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Data File C:\MSDCHEM\1\DATA\060702\12736.D Vial: 12 Acq On 7 Jun 2002 5:32 pm Operator: Sample Inst : Instrumen Miso : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 4-Chlorobuten-3-yne Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 3.73 4.65 ug/L 3252160 1,4-dichlorob'enzene-d4 9.89 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 4-Chlorobuten-3-yne 86 C4H3C1 040589-38 2 Propiolonitrile 51 C3HN 001070-71 3 4 3-Butyn-l-ol 3-Aminopropionitrile Abundance Scan 112 (3.737 min): 12736.D (-110) (-) 51 70 C4H60 70 C3H6N2 m/z 000927-74 000151-18 51.10 10 I 84 5000 88 70 42 3.40 3.60 3.80 4.00 01-mTH ■ ■ ■ i ■" ■ i ■ ■ ■ • i''" T ' i11 “ i • “ m/z 84.00 58.84% miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12405:4-Chlorobuten-3-yne 51 86

5000 3.40 3.60 3.80 4.00 m/z 88.00 42.58%

miz-> 0! 11 5 i1 ■ “ i • ■ • ■ i “ " ।“ i1 “ • i ■ “ • i ■■ ■ ■ i 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 H IR9-m 60 . "WMWww MAw Abundance #12371: Propiolonitrile 51 ' ' i ' 1 ‘ ‘ I ‘ ‘ ‘ ' I ' ' ' ■ I ' ' ' ■ I 3.40 3.60 3.80 4.00 5000 m/z 70.00 25.29%

nz-> O+ 5+12.18,4428,32. 38, 447. 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ' “ i ■"' । । ‘ । ■ i ■ ■" । ' ■i ■■ ■■ i ■■ ■■ । ■

Abundance #1400:3-Butyn-1-ol i ■ 1 ■ ' i ' 40 3.40 3.60 3.80 4.00 m/z 83.00 20.39% 5000

27 31

143,497756. 66 | 121518 i ■■■■I127lilJ■.u 37 0 '11 ‘11' i'''11111 ‘ ill 69 wpo/"PM* n/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.40 3.60 3.80 4.00

12736.D 060302.M Mon Jun 10 11:23:14 2002 Page 6

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