GCMS reference analysis results for volatile organics, June 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\060702\12735.D Vial: 11 Acq On 7 Jun 2002 4:43 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST9 8.L

Peak Number 14 Ethyl Chloride Concentration Rank 19 R.T. EstConc Area Relative to ISTD R.T. 5.21 0.29 ug/L 201859 1,4-dichlorobenzene-d4 9.89

Hit# of 5 Tentative ID MW MolForm CAS# Qu.

1 Ethyl Chloride 64 C2H5C1 000075-00-3/2 2 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 1 3 2-Chloroethanol 80 C2H5C10 000107-07/3 1 4 Ethanol, 2,2-dichloro- 114 C2H4C120 000598-38-9 1 Abundance Scan 362 (5.206 min): 12735.D (-360) (-) m/z 49.10 100.00% 40

5000 86

43

miz-> 0! 1 1 1 1 1 1 1 I ‘ ‘ 1 ' I ' 10 20 30 a 37

40 50 1 1 I ■ ‘ 60 70 ‘ I 1 1 1 1 I 80 90 100 110 120 130 4.80 m/z 5.00 86.00 5.20 5.40 5.60 42.39% Abundance #107943: Ethyl Chloride ??

64 5000 4.80 5.00 5.20 5.40 5.60 49 rn/z 51.05 21.20% 01 —hil 15 1 -- 35 ’I’’’’I’’+1++’’I’+-’1+’411’ ’’II "iAL... m/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #108005: Acetic acid, chloro-, ethyl ester 29

4.80 5.00 5.20 5.40 5.60 5000 rn/z 43.10 19.47% 42 49 n 14

n/z-> 01 - 10 20 +39— 30 40 50 60 70 | 88 94 ■ 11 1 . ■ • ■ । 80 90 । 100 107 । 110 122 । । 120 । . 130 Abundance #108293: 2-Chloroethanol ■ i • ■ ■ • i ' ■ ■ ■ i 1 ■ ■ ‘ i ‘ ' i ■ ■ 31 4.80 5.00 5.20 5.40 5.60 m/ z 81.90 16.84%

5000

0 .... 1 ' ‘ 37' I 43 49 80 1 1 ■ | ■ r > | 1 1 I . | 1 . I . |TT. 1 | I 61 ‘ | ‘ ■ l'|-l 11 ' 'T' ' ' . | f •j-r-r TT — m/z—> 10 20 30 40 50 60 70 80 90 100 110 120 130 4.80 5.00 5.20 5.40 5.60

12735.D 060302.M Mon Jun 10 11:22:57 2002 Page 17

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