GCMS reference analysis results for volatile organics, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C: \MSDCHEM\1\DATA\060702\12735.D Vial: 11 Acq On 7 Jun 2002 4:43 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 10 Piperidine, 1,1'-dithiobis- Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 4.25 1.86 ug/L 1294850 1,4-dichiorobenzene-d4 9.89 Hit# of 5 Tentative ID MW MolForm CAS# Qua 1 Piperidine, 1,1'-dithiobis- 232 C10H20N2S2 010220-20-9 /9 2 2-Amino-oxazole 84 C3H4N20 1000144-64/0 7 3 Methanethiol 48 CH4S 000074-93/1 7 4 Methanethiol 48 CH4S 000074-93-1 7

t Abundance Scan 200 (4.254 min): 12735.D (-197) (-) m/z 47.10 100.00% 47 84

5000 91 70 42

n/z-> 35 Ot "’101111311111111113111171107111

Abundance L ................ 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ' ■ i ■ ■ ■ ‘ i' m/z 4.00 4.20 84.00 4.40 4.60 68.06% #33817: Piperidine, 1,1’-dithiobis- 84

55 5000 4.00 4.20 4.40 4.60 41 m/z 48.10 55.86% 70 79

m/z-> ol ■ ■ l ■ ■ ■ • l ■ ■ ■111"11 ■111J1 •1 • 11111111111 5 ......... 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 kmmpmp Abundance #33688:2-Amino-oxazole 84

56 4.00 4.20 4.40 4.60 5000 m/z 88.00 40.29% 42

nz-> ol ■ ■ i1 ■ ■11 ■' ■ ‘ i ‘ • ■ ■ i “ TIWT 31 —44.51 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 1 ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i11 ■ ■ i ■ ■ • ■ ■ ■ ■ i1 ■ ■ ■ i ■ ■ ■ ■ i •

Abundance #12281: Methanethiol 47 4.00 4.20 4.40 4.60 m/z 91.10 37.40% 5000

33

miz-> 0- 5 14 -24., JU10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Hmmmmmmmmpmp ‘ 1 I ' 1 r ‘ 1 4 4.00 4.20 4.40 4.60

12735.D 060302.M Mon Jun 10 11:22:55 2002 Page 13

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