GCMS reference analysis results for volatile organics, June 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C:\MSDCHEM\l\DATA\060702\12735.D Vial: 11 Acq On 7 Jun 2002 4:43 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak. Number 9 Ethenamine, N-methyl-N-nitr... Concentration Rank 13 R.T. EstConc Area Relative to ISTD R.T. 4.22 0.79 ug/L 553843 1,4-di chiorobenzene-d4 9.89

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Ethenamine, N-methyl-N-nitroso- 86 C3H6N20 004549-40-0/5 2 2-Propanone, methylhydrazone 86 C4H10N2 005771-02-8 5 3 Phosphonic difluoride 86 F2HOP 014939-34/5 5 4 1,3-Dioxol-2-one 86 C3H203 000872-36-6 5 Abundance Scan 195 (4.225 min): 12735.D (-193) (-) m/z 86.00 100.00% 85

41 49 5000 37 70 i ■ ■ ■ ■ i ■ ■ 3.80 4.00 4.20 4.40 4.60

n/z-> 01 ’I’’*11' 1 ‘ ‘* 20 25 30 4 111 “ — ■ 111 ■ 11111111111

35 40 45 50 55 60 65 70 75 80 85 1 ■ i ■ ■ ■ ■ i ■1 i111 n ■ 90 95 m/ z 84.00 70.69% Abundance #737: Ethenamine, N-methyl-N-nitroso- 33 42

5000 i ■ ■ ' ■ i ' 1 1 1 I ' 1 ' 'r 1 1 1 57 3.80 4.00 4.20 4.40 4.60 m/z 49.10 53.45% Ot 133 363 11,47.511 54 67— 80 83 86 11111111111 r 111111111111111111111111 r-| । ■ I' ' '' I ' m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #885:2-Propanone, methylhydrazone 33 86

3.80 4.00 4.20 4.40 4.60 42 50001 56 m/z 41.00 48.28% 71

Tl/Z-> Abundance Ot al 20 25 27

30 + mp -pm "Woron/., 35 39

40 45 50 55 60 65 70 75 80 85 90 95 #34889: Phosphonic difluoride 85 3.80 4.00 4.20 4.40 4.60 m/z 51.00 43.10% 5000 69

66 47 31 50 0 ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ ।1 ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ 111 " 11 " " I i1 •' ■ i' ■1 ■ r ■ " 111'1 f miz—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.80 4.00 4.20 4.40 4.60

12735.D 060302.M Mon Jun 10 11:22:53 2002 Page 12

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