GCMS reference analysis results for volatile organics, June 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\MSDCHEM\1\DATA\060702\12735.D Vial: 11 Acq On 7 Jun 2002 4:43 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 7 2,3,4,5-Tetrahydropyridazine Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 4.11 1.41 ug/L 980924 1,4-dichlorobenzene-d4 9.89 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2,3,4,5-Tetrahydropyridazine 84 C4H8N2 000694-06-4 10 2 Piperidine 85 C5H11N 000110-89-4 9 3 Piperidine 85 C5H11N 000110-89-4 9 4 Azetidine, 1-nitroso- 86 C3H6N2O 015216-10-/ 7 Abundance Scan 175 (4.107 min): 12735.D (-173) (-) m/z 86.00 100.00% 85

5000 55 41 89 47 38 ■ ■ i ■ ' ■ ■ 1 1 1 1 1 I 2E t 44 3.80 4.00 4.20 4.40

n/z-> i 31 O+ pT-TTp-rTTp-rTTp-rTTp-TT^ 'i"" 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 83 TTp-rrrp-TTTp-rrTp-rrrp-r^ i" ■ ■ r11 m/ z 84.00 88.37% Abundance #33489:2,3>4,5-Tetrahydropyridazine 28 84

5000 55 41 3.80 4.00 4.20 4.40

,Mws/ 69 m/z 85.00 56.41% 14

m/z-> 0 i ■ ■ ■ ■ i' ■" i • ■ • ■ i" ■ ■ i —Mri 1’11153 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 i “ " i ■ “ ■ i"

Abundance #116601: Piperidine 84 ■ • ■ ।1 ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ ।

3.80 4.00 4.20 4.40 5000 m/z 55.10 48.45% 56 29 .44 70

m/z-> Of I5 -255 7 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 1 63 67 । 76 80,,

Abundance> #116576: Piperidine i 1 ■ ■ ■ i ‘ ‘ ’I 84 3.80 4.00 4.20 4.40 m/ z 89.00 38.44% 56 5000 28 44 41 15 — 32 38 | 50531 6770 80 0 TTHHT taapandllponnaquadlilny ptH —pmpT m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 3.80 4.00 4.20 4.40

12735.D 060302.M Mon Jun 10 11:22:49 2002 Page 10

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