GCMS calibration data sample AE12098, June 2002

NYC 9/11 Public Portal Document Quantitation Report (QT Reviewed)

7 Data File C:\HPCHEM\l\DATA\MAY3102\CAL40.D Vial: 2 Acq On 31 May 2002 12:55 pm Operator : Morgan Sample Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Jun 3 9:20 2002 Quant Results File:rGCMS0531.RES Quant Method : C:\I1PCHEM\1\METHODS\GCMS0531.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri May 31 09:43:55 2002 Response via : Initial Calibration DataAcq Meth : GCMS0531

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.06 152 406965 40.00 ug/1 -0.02 10) Naphthalene-d8 15.70 136 1639549 40.00 ug/1 -0.02 17) Acenaphthene-diO 20.99 164 780468 40.00 ug/1 0.00 30) Phenanthrene-diO 25.43 188 1244961 40.00 ug/1 0.00 38) Chrysene-dl2 33.48 240 823132 40.00 ug/1 -0.03 44) Perylene-dl2 37.66 264 541224 40.00 ug/1 -0.03

System Monitoring Compounds 28) TCMX 23.13 209 236890 43.87 ug/L -0.02 Spiked Amount 40.000 Recovery = 109.68% Target Compounds 287 Qvalue 2) N-nitrosodimethylamine 5.73 74 532017 42.69 ug/1 100 3) bis(2-Chloroethyl)ether 11.47 93 710877 43.67 ug/1 98 4) 1,3-Dichlorobenzene 11.96 146 714359 44.17 ug/1 99 5) 1,4-Dichlorobenzene 12.11 146 780431 44.56 ug/1 100 6) 1,2-Dichlorobenzene 12.62 146 686158 44.51 ug/1 100 7) 2,2'-oxybis(1-Chloropropan 12.95 45 1080143 42.47 ug/1 98 8) N-Nitrosodi-n-propylamine 13.34 70 488700 43.45 ug/1 98 9) Hexachloroethane 13.47 117 308169 44.56 ug/1 97 11) Nitrobenzene 13.74 77 669007 44.19 ug/1 99 12) 1sophorone 14.39 82 1248234 43.95 ug/1 98 13) bis(2-Chloroethoxy)methane 15.08 93 820421 43.97 ug/1 99 14) 1,2,4-Trichlorobenzene 15.59 180 582033 45.80 ug/1 98 15) Naphthalene 15.75 128 1960873 45.45 ug/1 100 16) Hexachlorobutadiene 16.30 225 254882 45.55 ug/1 100 18) Hexachlorocyclopentadiene 18.49 237 213369 44.57 ug/1 98 19) 2-Chloronaphthalene 19.25 162 933432 44.90 ug/1 100 •20) Dimethylphthalate 20.35 163 1192682 45.14 ug/1 99 21) 2,6-Dinitrotoluene 20.56 165 272058 45.59 ug/1 98 22) Acenaphthylene 20.53 152 1702355 45.64 ug/1 100 2 3) Acenaphthene 21.09 153 1024939 45.63 ug/1 99 24) 2,4-Dinitrotoluene 21.73 165 312786 44.78 ug/1 98 25) Diethylphthalate 22.48 149 1101581 45.02 ug/1 99 26) 4-Chlorophenylphenylether 22.63 204 550841 47.33 ug/1 98 27) Fluorene 22.61 166 1081306 47.39 ug/1 100 29) Azobenzene 23.10 77 1319341 43.65 ug/L 99 31) N-Nitrosodiphenylamine 23.02 168 412510 45.38 ug/1 98 32) 4-Bromophenylphenylether 24.10 248 284219 45.50 ug/1 97 3 3) Hexachlorobenzene 24.53 284 313445 45.82 ug/1 99 3 4) Phenanthrene 25.49 178 1617680 46.23 ug/1 100 (#) = qualifier out of range (m) = manual integration CAL40.D GCMS0531.M Mon Jun 03 09:22:07 2002 Page 1

NYC-WTC_0000 14872