GCMS analysis results, sample AE12478, June 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052902\12478.D Vial: 20 Acq On : 30 May 2002 1:34 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 12 Formamide, N-(cyanomethyl)- Concentration Rank 14 R.T. EstConc Area Relative to ISTD R.T. 5.06 0.28 ug/L 197453 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Formamide, N-(cyanomethyl) - 84 C3H4N2O 005018-27-9 7 2 4-Methylproline 129 C6H11NO2 1000131-14-6 7 3 2-Butenoic acid, 3-amino-, ethyl... 129 C6H11NO2 007318-00-5 5 4 Perdeuterobenzene 84 C6D6 001076-43-3 4 Abundance Scan 338 (5.065 min): 12478.D (-335) (-) m/z 84.00 100.00% 84

5000 47 35 56 166 131 ' ' 4.80 5.00 5.20 5.40 0 1Tu—B1r m/z 47.05 46.44%

"WWALw । । । i ■ । i rri | i i ■ ■ । i ■ n-j-i i „ | । । . Tp-T

m/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #541: Formamide, N-(cyanomethyl)- 23

84 55 5000 4.80 5.00 5.20 5.40 40 m/z 165.80 28.08% 66 Or +4444 mp 1 ■ i.1 ■ ■ ■ i ■1 ■ • i ■' ■ ■ i ■ ■■ • i ‘ ‘ ■ i ■ ■ • ■ i‘ ■ i ■' ■ ■ i ■ ■ m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #33527:4-Methylproline 84 ■ ' i ■ ■ ■ ■ i ■ ■ ■ । ■ i ■ ■ ■ ■

4.80 5.00 5.20 5.40 5000 m/z 35.10 27.26%

o ----- 66 41 73 56 । 92 101 112 128 [| ■1 rl’’t "I1' 1 ■ i ■ ■ ■ ■ i • ■ • • i ■ ■ ■ ■ i ■ 1 ■ ■ ■ ■ i ■ • ‘ • i111 ■ i ■ ■ • ■ i ■ ■ " 1 "MMAll A Th m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #33723:2-Butenoic acid, 3-amino-, ethyl ester A l. 57 84 4.80 5.00 5.20 5.40 m/z :39.10 25.07%

5000 42

29 68 129

0- 191 114 1 444l 4 TTpf 1. . ।|। 1.. ।... 11 .'j.. 111।।।. iz—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 4.80 5.00 5.20 5.40

12478.D 052202.M Mon Jun 03 11:40:38 2002 Page 15

NYC-WTC_000014479