GCMS analysis results for sample AE12474, June 2002

NYC 9/11 Public Portal Document ulprary bearcn compound Report

Data File : C:\MSDCHEM\1\DATA\052802\12474.D Vial: 12 Acq On : 28 May 2002 11:15 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************* * * ********** Peak Number 5 Propiolonitrile Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T. 3.88 1.61 ug/L 991618 1,4 -Dichlorob'enzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Propiolonitrile 51 C3HN 001070-71-9 4 2 Pent-4-enylamine 85 C5H11N 022537-07-1 A 3 Piperidine, 1,1'-dithiobis- 232 C10H20N2S2 010220-20-9/2 4 4-Chlorobuten-3-yne 86 C4H3C1 040589-38-6 2 Abundance Scan 137 (3.884 min): 12474.D (-136) (-) m/z 51.10 100.00% 51 84

5000 88 43 ' ■ ' ■ i ■ ■ ■ ■ i ■ ' ‘ • i ■ ■ ■ • । • 36 58 3.60 3.80 4.00 4.20

mfe-> 0 1’0111219111077009700—00—220’11111" TTT a ■ i ■ ■" i' • 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 m/z 84.00 68.28% Abundance #12371: Propiolonitrile 51

5000- 3.60 3.80 4.00 4.20 m/z 82.90 55.51%

miz-> 01 5. 10........................................ TnU’)011Upmep 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #745: Pent-4-enylamine 30

3.60 3.80 4.00 4.20 5000 m/z 85.00 44.27%

43 « 27 39 00 e- Of | 11 146 5053 | mmm HrTLtHmmpr 63 1170 84 miz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #33817: Piperidine, 1,1’-dithiobis- 84 3.60 3.80 4.00 4.20 m/z 88.00 43.83%

5000]

4144 52 55

81 w,"Mol n/z—> 0 -l 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ++ —64677° —mmm 3.60 3.80 4.00 4.20

12474.D 052202.M Thu May 30 10:42:59 2002 Page 8

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