GCMS analysis results for sample AE12327, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052802\12327.D Vial: 7 Acq On : 28 May 2002 7:11 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) *** Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 6 Borane, trifluoro- Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T.

4.04 2.46 ug/L 1358380 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Borane, trifluoro- 68 BF3 007637-07-2 1 2 Propanoyl chloride 92 C3H5C10 000079-03-8/1 3 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-/ 1 4 Ethyl Chloride 64 C2H5C1 000075-00/3 1 Abundance Scan 164 (4.043 min): 12327.D (-162) (-) m/z 49.10 100.00% 40

5000 86 40 3.60 3.80 4.00 4.20 4.40 - 58 0- -PHr p ‘d‘ । ■ ‘ ■ ■ । ■ ■ ■' । IT m/z 47.10 45.83% nz-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 ... Abundance #12321: Borane, trifluoro- 40

5000 3.60 3.80 4.00 4.20 4.40 m/z_ 86.00 28.55% 11 1? 30 38 68 0- - Immpi t • • • * t • —mpmppmmmpmp miz-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #472: Propanoyl chloride 29 57 । ■11 ■ ■ • ■ ।1 ‘1 ■ । ■ ■ • • । ■ 3.60 3.80 4.00 4.20 4.40 5000 m/z 40.05 12.94%

14 0- 2 o'' —4 -4 , 42 49 I,65 । . . . , 91 .7, . 182 . । 73 ।. 111 ■ ■ ।' ■' ■ । IT miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #108005: Acetic acid, chloro-, ethyl ester 20 3.60 3.80 4.00 4.20 4.40 m/z 44.10 10.11% 5000

14 42 49 77 ‘* U /z-> o- ml 0 "T1,1,111,159/66/111,1.85 94 107 122 10 20 30 40 50 60 70 80 90 100 110 120 130 ■ i ■ It a i ■1 i ■ ■ ■ ■ i' ■ ■ ‘ i ■ 3.60 3.80 4.00 4.20 4.40

12327.D 052202.M Thu May 30 10:41:11 2002 Page 8

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