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← Document results/DEP Box 15/GCMS X 5/24/02 A 5/28/02
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GCMS calibration table for TCLP extraction method

Machine-extracted title · confidence 90%

GCMS analysis results for sample AE12287 dated June 4, 2002, documenting unknown compounds and surrogate recovery.

NYC-WTC_000014004–000014032

Folder label: “GCMS X 5/24/02 A 5/28/02

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NYC 9/11 Public Portal Document Llorary searen compound Keport

Data File : C:\MSDCHEM\1\DATA\052802\12287.D Vial: 6 Acq On : 28 May 2002 6:22 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 20 IH-Pyrrole, 1,1',1''-boryli... Concentration Rank 17 R.T. EstConc Area Relative to ISTD R.T.

34.90 0.27 ug/L 115124 Perylene-d12 34.65

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1H-Pyrrole, 1,1' , 1" -borylidynet. . . 209 C12H12BN3 018899-90-6 7 2 Quinoline, 2-(1-methyl-lH-imidaz... 209 C13H11N3 002552-97-8 7 3 4-Methylbenzylidene-4-methylaniline 209 C15H15N 016979-20-77 4 2-Propen-1-one, 1,3-diphenyl- 208 C15H120 000094-41-7 7 Abundance Scan 5416 (34.901 min): 12287.D (-5413) (-) m/z 2 0 7.00 100.00% 207

5000 116 260 uMrshawaluth 44 147 281 73 34.60 34.80 35.00 35.20 O-T 1 ■ i' ■ ■ ■ i' ■' • i ■ ■ i ■ ‘■ i ■ ' ■ ■ i ■ ■' ■ i ■ ■ ■ ■ i' ■ ■ i1 1 ■ ■ i11 I m-r-p-r m/z 208.00 66.75%

l nz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #85124: 1H-Pyrrole, 1,1’,1"-borylidynetris- 208

5000 “rnnt 34.60 34.80 35.00 35.20 143 m/z 209.00 51.54% 116 , 63 76 89

iz-> 0 20 27,4,51,44.78.4,104 +,128.4.1551714... 40 60 80 100 120 140 160 180 200 220 240 1 ■ I ■ ■' ■ i •' ■ ■ i' ‘ 260 280 ■ i ■1

Abundance

5000 #85119: Quinoline, 2-(1 -methyl-1 H-imidazol-5-yi)- 208 LMahdasusn 34.60 34.80 35-00 35.20 m/z 260.10 48.93% 77 128I 155 102 140 OA [ 11111111 11 ■ । ,44% 1114 .. J I I, 168 181193 T * I' • ‘ ‘ I ‘ 1 • * 1 ‘ ‘ 1 ' I *1 miz-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #85332:4-Methylbenzylidene-4-methylaniline ----1 209 34.60 34.80 35.00 35.20 m/z 116.10 41.81% 50001 91

65 27 39 51 | 77 . 103 118,30 149 165178 194 , 14 0- Tm ■. . । , . . . ( i i-n -| i i ■ i । i i n/z—> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 34.60 34.80 35.00 35.20

12287.D 052202.M Thu May 30 10:40:38 2002 Page 23

NYC-WTC_000014031

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NYC-WTC_000014031Source: NYC Law Department, mirrored locally

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