GCMS calibration table for TCLP extraction method

NYC 9/11 Public Portal Document Llorary bearen compound Report Data File : C: \MSDCHEM\ 1 \DATA\05280212287.D Vial: 6 Acq On : 28 May 2002 6:22 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integfator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 11 3-Methoxybut-l-ene Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 4.90 0.50 ug/L 341831 1,4-Diehlorobenzene-d4 9.90 Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 3-Methoxybut-1-ene 86 C5H10O 017351-24-5 27 2 3-Methoxybut-1-ene 86 C5H10O 017351-24-5 16 3 2-Butene, 4-methoxy 86 C5H10O 018408-99-69 4 1-Butene, 1-methoxy- 86 C5H10O 029512-02-5 9 Abundance Scan 309 (4.895 min): 12287.D (-304) (-) m/z 71.10 100.00% 43 71

5000] 86 47 59 38 55 ’ ’I**’*I**’I+444)’ ’’L

0 --lll V T ’ 14* +. ‘ I ' ' ‘ ' I ' m/z 4.60 4.80 43.10 5.00 5.20 82.96% /z-> Abundance 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95

41 #114479:3-Methoxybut-1 -ene 7 MMwa/iwpuwos 55 5000 59 ■ ■ i • • ■ ■ i ■ ■ 29 86 4.60 4.80 5.00 5.20 m/z 69.10 45.63%

m/z-> 0+ ■ ■ i ■ ■ " i ■ 20 25 38 TPH 30 1 35 40 414 —mpum 45 50 55 60 65 70 75 80 85 11) 90 95 Abundance #24260:3-Methoxybut-1-ene 7h 41 • • i • • > ■ i • I ' 1 ' 1 I 1 1 1 1 I 55 4.60 4.80 5.00 5.20 5000 m/z 41.10 40.67% 59 86 31 45

^z-> Al1#++ ML I 38 0! 11 • • ■ ■ i ■ .. 11 ■.. i ■ m; p+ 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 51 I • ■1 ■ i ■ ■ ■ ■ i ■ ii ‘ • i *

Abundance #24258: 2-Butene, 4-methoxy ■ 1 ■ । • 1 • ' । • 'i • ■ • • । ■ ■ ■ ■ । 71 4.60 4.80 5.00 5.20 m/z 86.00 39.05% 41 55 5000 29 86 45

38 51 m/z-> ml ++ -H 0 ‘' i “ ■ ■ i1 mH Ipanuagui 1 ■ < i ■»■ ■ i > 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 ' ■ i ‘ ‘ ■ l 1 ‘ ' I 1 ' 1 ' I ' ' ' 1 I 4.60 4.80 5.00 5.20

12287.D 052202.M Thu May 30 10:40:29 2002 Page 14

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