GCMS calibration table for TCLP extraction method

NYC 9/11 Public Portal Document Library bearen compound Keport Data File : C:\MSDCHEM\1\DATA\052802\12287.D Vial: 6 Acq On : 28 May 2002 6:22 pm Operator: McLean Sample : 5/24 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 9 Ethyl Chloride Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 4.36 1.62 ug/L 1097240 1,4-Dichlorob'enzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Ethyl Chloride 64 C2H5C1 000075-00-3 2 2 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 2 3 Acetic acid, dichloro-, ethyl ester 156 C4H6C12O2 000535-15-9 1 4 Difluorine monoxide 54 F20 007783-41-7 1 Abundance Scan 217 (4.354 min): 12287.D (-215) (-) m/z 35.10 100.00% 35 49 MMWM 50001 "MhM ■ 1 i ■ ■ ■ ■ i ■ ■ ' 1 i • • ■ ■ i ' 4.00 4.20 4.40 4.60 4.80 0+ W'i ■ If. ■ ■ ।.......... I'T........... ....................... ......... m/z 49.10 96.76% niz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #107943: Ethyl Chloride 28

64 5000 4 00 4.20 4.40 4.60 4.80 49 m/z 41.05 . 22.09%

niz-> Abundance • 0L H 15 I —Ht ■ i ■ " ■ i ‘ 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 29 " i' ■ " i ■ “ ■ i ■1 ■ ■ i' • ■' i ■ • “ i ‘1" i •1 " i “

#108005: Acetic acid, chloro-, ethyl ester "WMWWouhM 4.00 4.20 4.40 4.60 4.80 5000 m/z 37.10 13.58% 77 49 14

miz-> 01 M U4+4459.67/ | 85 94 107 122 * IT, ****14 IT. L**t***t*U**72*T+* 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #334: Acetic acid, dichloro-, ethyl ester 29 4.00 4.20 4.40 4.60 4.80 m/z 48.00 12.03% 5000

48 83 0 .. ।. 19, all) 37 l . 57, 65, 73), 4, 93. 102.111 121129.141, 155, ■ ■ । ■ ■ ' ■ । ■ ■ ■ ■ । 1 1 ■ ■ । ■ ■ ■ ■ । ■ ■nfz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 4.00 4.20 4.40 4.60 4.80

12287.D 052202.M Thu May 30 10:40:28 2002 Page 12

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