GCMS calibration table for TCLP extraction method

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Data File : C:\MSDCHEM\l\DATA\052802\11603.D Vial: 9 Acq On : 28 May 2002 8:49 pm Operator: McLean Sample : 5/24 ad re-ext Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 1 Acetonitrile, dichloro- Concentration Rank 14

R.T. EstConc Area Relative to ISTD R.T.

3.55 0.29 ug/L 206536 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Acetonitrile, dichiorO- 109 C2HC12N 003018-12-0 778 2 Acetonitrile, dichloro- 109 C2HC12N 003018-12-0 39 3 Cyclopentanemethano 1, 1-amino- 115 C6H13NO 010316-79/7 9 4 Thiophene 84 C4H4S 000110-02-1 5 Abundance Scan 80 (3.549 min): 11603.D (-74) (-) m/ z 74.00 100.00% 74

84 5000

38 47

58 ._ P__ 3.20 3.40 3.60 3.80

miz-> O+ ' ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i ■ 10 20 30 111—47 40 50 60 70 ■ । • i 80 ... 90 100 110 m/z 84.00 . 50.60% Abundance #28338: Acetonitrile, dichloro- 74

5000 82 * | 1 ' ‘ | ‘ ‘ ‘ 4 • ‘ ‘ ‘ | * I ' 3.20 3.40 3.60 3.80 47 m/z 82.00 49.62% 35

n/z-> 01 ' 1 1 10 12 ' 1 1 1 201 230—40 -—2-7 50 60 70 80 . 108 1**Iti ' 'T1 11 1 1 90 100 110 Abundance #115342: Acetonitrile, dichloro-

35 74 MonleyllrMrwe 3.20 3.40 3.60 3.80 5000 82 m/z 76.00 31.48% 47

Of 1*1**g —hen -r-r-p-r-r-t-p- 90 1 ■ ।' । ■ ■ ■ • । ■ 100 110 miz-> 10 20 30 40 50 60 70 80 Abundance #33745: Cyclopentanemethanol, 1-amino- 84 11g ’ I’I’ 3.40 3.60 3.80 3.20 m/z 47.05 30.43% (MWAw 5000 MMr/ 41 67 73 9 30 56

n/z—> 0: .... 10 18,20. ■ il) 30 .. 40 50 60 70 80 | 90 1 ■ i ■ ■ • ■ i ■ ■ ■ • i ■ ■ • ■ i 100 110 * i ‘ 3.20 ■ i ■ ■ 1 • i ■ • ■ ■ i ■ ■ ■ ' i 1 3.40 3.60 3.80

11603.D 052202.M Thu May 30 10:38:51 2002 Page 4

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