GCMS analysis results for sample AE11926, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052302\11927 .D Vial: 7 Acq On : 23 May 2002 2:51 pm Operator: Mclean Sample : 5/22ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 6 1,3,5-Cycloheptatriene Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 4.27 1.17 ug/L 727980 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qu.

1 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 / 2 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2/4 3 Bicyclo[3.2.0]hepta-2,6-diene 92 C7H8 002422-86-/ 4 4 1,6-Heptadiyne 92 C7H8 002396-63/6 4 Abundance Scan 202 (4.266 min): 11927.D (-198) (-) m/z 91.05 100.00% 91

5000

0- .. ।... * ।. ।. *. ■ ।t 39

T+ 51

58 1 65 1*19199 83 ‘ . I ‘ ‘ ‘ I ' ‘ m/z ■ ■ i ■ ■ ■ ■ i 4.00 4.20 4.40 4.60 92.05 60.13% s.. miz-> 0 10 20 30 40 50> 60 70 80 90 100 110 Abundance #117298:1,3,5-Cycloheptatriene 91

5000 ■ I ■ 1 1 I ■ I I 1 I I I I I 4.00 4.20 4.40 4.60 ______ 65 m/z 51.10 34.27% 28 39 I 01 TTP0—99r*t 45 51 -—4+ i • *’77**4 i ' 85 I , ■ ■ i • ■ ■ ■ i ‘ ■ miz—> 0 10 20 30 40 50 60 70 80 90 100 110 Abundance #37276:1,3,5-Cycloheptatriene 91 ■ ■ ■ ■ i ■ ■ ■ 1 । ' ■ 1 ■ । ■ ■ ■ ■ । ■ • • ' 4,00 4.20 4.40 4.60 5000 m/z 39.20 25.50%

39 65 2 15 27 ,I 45 51 57 . 71 77 85 , 0- - 106 1+1‘‘‘I41‘I* lT‘,|1i ‘T1’1 ■ 1 ’ll ■ l ■ 11*1 IT TI n/z—> 0 10 20 30 40 50 60 70 80 90 100 110 Abundance #37273: Bicyclo[3.2.O]hepta-2,6-diene 91 4.00। 4.20 4.40 4.60 m/z :38.10 17.63%

5000 / 1 39 66 0 .............. 27 ..... ...... dl........... ‘ 4 I * ' * * I * ‘ 4 4 I 4 r ' 4J « i I ‘ | i J : » I » I I » | I 'I i | i * * * | I * I l |‘I m/z-> 0 10 20 30 40 50 60 70 80 90 100 110 4.00 4.20 4.40 4.60

11927.D 052202.M Wed May 29 09:48:14 2002 Page 9

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