GCMS analysis report sample AE09678, May 23, 2002

NYC 9/11 Public Portal Document Library searcn compounu Report Data File : C:\MSDCHEM\1\DATA\052102\9678.D Vial: 16 Acq On : 22 May 2002 1:33 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 5 Propanoyl chloride Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 3.95 3.59 ug/L 2093710 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Propanoyl chloride 92 C3H5C1O •000079-03-8 9/ 2 Perdeuterobenzene 84 C6D6 001076-43-3 2 3 Krypton 84 Kr 007439-90-9 2 4 Propanoyl chloride 92 C3H5C10 000079-03-8 2 Abundance Scan 148 (3.949 min): 9678.D (-147) (-) m/z 43.10 100.00% 43 84 AM"T"MMWWMussy 5000 36 48

3.60 3.80 4.00 4.20 4.40

m/z-> 0- 1 ■ i ‘ 0 ■ i ■ ■ ■ ‘ i ■ ■ 1 ‘ I 1 ■ 10 20 30 TTf 40 11150 60 ' ' i ■ 1 ■ ■ i ■ ‘ 70 ■ i 1 80 90 100 m/z 84.00 76.84% Abundance #472: Propanoyl chloride 29 57

5000 3.60 3.80 4.00 4.20 4.40 m/z 87.00 70.62%

"MI 35 42 49 65 71— 76m0////n/// 82 91 —,1/8m 0- *1n*n/ 60 . 70 80 90 100 n/z-> Abundance 0 10 20 30 40 50 #33650: Perdeuterobenzene N 84 "I 3.60 3.80 4.00 4.20 4.40 5000 m/z 36.10 47.74% 42 52

-2-18+3 — + 157 I ■ 166I < । । 1176 ■ N I 0- ■ ■ i ■ • ■ ■ i ■ niz-> 0 10 20 30 40 50 60 70 80 90 100 Abundance #33829: Krypton ■ ■ i ■ • • ■ i ' ■ ■ ■ i ■ ■ ' ■ i ■ ■ ■ ■ i ■ 84 3.60 3.80 4.00 4.20 4.40 m/z ./ 35.10 46.05% 5000 Mrw 42

n/z-> 0 0 10 20 30 40 । _ _________ 1 ■ • i ■ ■ • ■ i ■ ■ ■ ‘ i ' 50 60 70 7880 111 ■ ■ ■ ।' 90 100 3.60 3.80 4.00 4.20 4.40

9678.D 052202.M Wed May 22 11:43:23 2002 Page 8

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