GCMS sample analysis results, AE11907, June 4, 2002

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Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052202\11907.D Vial: 14 Acq On : 23 May 2002 12:25 am Operator: Mclean Sample : 5/21 ad Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 9 4,7-Dimethyl-l,10-phenanthr... Concentration Rank 16 R.T. EstConc Area Relative to ISTD R.T. 5.38 0.22 ug/L 128472 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 4,7-Dimethyl-l,10-phenanthroline 208 C14H12N2 003248-05-3 3 2 5H-Dibenzo[a,d]cyclohepten-5-one... 208 C15H120 001210-35-/5 3 4,6-Dimethoxy-5-vinyl-l,2-benzod... 208 C11H1204 079553-88-1 3 4 1H-1,2,4-Triazole, 3-ethyl-5-(5-... 208 C8H8N4O3 005019-57-8 3 Abundance Scan 391 (5.377 min): 11907.D (-387) (-) m/Z 35.10 100.00% 35 MMMMMA/A 5000 49 96 208 (Wmtu A

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01 ■ ■ । ■ Li *’1**’I* l i ■ ■ • 1 i ' ■ ' ■ I ■ ■ ■ ■ i ■ ' ' ‘ i ‘ ‘ ' I ' 5.00 m/z 5.20 43.10 5.40 5.60 71.99% 5.80

miz-> Abundance 20 40 60 80 100 120 140 160 #126530:4,7-Dimethyl-1,10-phenanthroline 180 200 208 "MMMMwwd 5000 5.00 5.20 5.40 5.60 5.80 m/z 208.00 62.31% 18 28 39 51 63 76 90 104 115 127 140 152 166 180 193 , Of --------------- miz-> 20 40 60 80 100 120 140 160 180 200 Abundance #126511: 5H-Dibenzo[a,d]cyclohepten-5-one, 10,11 -dihydro- 208 180 5.60 5.80 500 5.20 5.40 5000 m/z 209.00 48.39% 165 89 51 63 76 152 193

miz-> O+ 20 40 l 60 80I „ 103 115 126 139 । —-I_ ।_ I r i *! n i h—i—y 100 120 140 ■ 1’* ■ ’* 160 180 200 Abundance #85028:4,6-Dimethoxy-5-vinyl-1,2-benzodioxole 208 5.00 5.20 5.40 5.60 5.80 163 m/z 49.10 46.69% 193 5000 107 135 53 64 77

0 ■ ■ i ■ ■ ■ ' । ■1 ■ ' । ■ ■ ■ ■ । ■ ■ 1 ■ ■ । ■ ■ ■ ■ । ■ n/z-> 20 40 60 80 100 120 140 160 180 200 5.00 5.20 5.40 5.60 5.80

11907.D 052202.M Tue May 28 12:14:25 2002 Page 12

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