GCMS sample analysis results, AE11901, June 4, 2002

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Library Search Compound Report Data File : C:\MSDCHEM\l\DATA\052202\11901.D Vial: 8 Acq On : 22 May 2002 7:31 pm Operator: Mclean Sample : 5/21 ad Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e 2"* Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 11 2-Methyl-6-(5-methyl-2-thia... Concentration Rank 18 R.T. EstConc Area Relative to ISTD R.T. 5.37 0.46 ug/L 307816 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2-Methyl-6-(5-methyl-2-thiazolin... 207 C10H13N3S 1000225-39-3 5 2 1,3,5-Triazine, 2-chloro-4 ,6-bis... 207 C5H6C1N3S2 004407-40-3/5 3 N-(2-Acetylcyclopentylidene)cycl... 207 C13H21NO 1000100-48/5 4 4 Corydaldine 207 C11H13NO3 000493-49/2 4 Abundance Scan 390 (5.371 min): 11901 .D (-383) (-) m/z 207.05 0.00% 207

5000 96 84 191 __,0000/ 43 ro miz-> 0- A.+FR.++Hm 11001—01—0100001110111011100011000010007/777 I ‘ 30 40 50 60 70 80 90 100110120130 140150160 170180 190 200 210 ‘! 5 00 5.20 5.40 5.60 5.80 m/z 209.00 39.42% Abundance #84743:2-Methyl-6-(5-methyl-2-thiazolin-2-ylamino)pyridine 207 93 165 65 119 133 5000 ■ • i ■ ■ ■ ■ i ■ 39 147 5 00 5.20 5.40 5.60 5.80 107 m/z 208.00 37.10% 56 ? 174 192 0 । ■ i, ri i'l {1477p/71 ills? ++ 11’ mmmm 4 niz-> 30 40 50 60 70 80 90 100110 120130 140150160 170180 190200 210 Abundance #84733:1,3,5-T riazine, 2-chloro-4,6-bis(methylthio)- 207 74 500 5.20 5.40 5.60 5.80 5000 45 146 m/z 96.00 32.16% 87 160 58 99

n/z-> a.. 1110 121 134 „ 173 0-... nipi mhH ■ ’’’I । ■ "’l 1111111111111111 ii 1111 1’31 ' 11"11 ,l|~' 11 * * * 111111111 Im 192

30 40 50 60 70 80 90 100110 120130 140150160 170180 190200210 Abundance #84801: N-(2-Acetylcyclopentylidene)cyclohexylamine ■ i • ■ ■ ■ i ■ 1 • ■ i ' • • • i • 207 5.00 5.20 5.40 5.60 5.80 164 m/z 191.00 23.39% 124 41 5000 55 67 82 97 110 150 192

m/z-> 0- 136 • । ■ ■1 • । ■ •' ■ 30 40 50 60 70 80 90 100110 120130140150160 170 180 190 200 210 ■1 ■ ■ i1 H 178 “i ■• i ■ “■i 5.00 5.20 5.40 5.60 5.80

11901.D 052202.M Tue May 28 12:05:43 2002 Page 14

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