GCMS analysis results for sample AE03075, March 5 2002

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Library Search Compound Report : Data File : C:\MSDCHEM\1\5973N\02FEB28\02714.D Vial: 4 Acq On : 28 Feb 2002 1:00 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 28, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L Peak Number 6 DEUTEROACETONE Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 5.02 0.05 ug/L 20859 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 DEUTEROACETONE. 59 C3H5DO 004468-52-4 4 2 (Aminomethyl)cyclopropane 71 C4H9N 002516-47-4 3 3 Pyrrolidine (CAS) $$ Prolamine $... 71 C4H9N 000123-75-1 3 4 Butane, 1-bromo-2-methyl- (CAS) ... 150 CSHllBr 010422-35-2 2 Abundance Scan 146 (5.022 min): 02714.D (-) m/z 41.10 100.00% 4143 71

5000 69 49 555759 4.60 4.80 5.00 5.20 5.40 O+ ‘ ■ i ■ ■1 • i ■ • ■ ‘ i114 ■ । ' ■11' ■ 1 i • • i *1 ' I 1 * ‘ * t ‘ ‘ * I -r-r-p-r-r-r-p- m/z 43.00 90.32% ?niz~> 20 25 30 35 40 45 50 55 60 65 70 75 80 Abundance #587: DEUTEROACETONE 43

5000 59 AAAA 4.60 4.80 5.00 5.20 5.40 45 m/z 71.00 83.05% 31 373941 O+ 1PTTPTTTTII++++ TBGuina . । i . ’1**4/14*’I141* niz-> 20 25 30 35 4045 50 55 60 65 70 75 80 Abundance #1489: (Aminomethyl)cyclopropane 43 N 30 i ■ ■ ■ ■ i • ■ 11 *+114* 4.60 4.80 5.00 5.20 5.40 5000 m/z 69.10 36.06%

27 71 34 38 , 01 ■ ■ i1 ■ — —p +1WTTI9———m1 ■ ' i * ■ ‘ ■ I ■ ........ 5456 .......... 68 || miz-> 20 25 30 35 40 45 50 55 60 S5 70 75 80 Abundance #1475: Pyrrolidine (CAS) $$ Prolamine $$ Azolidine $$ Buty... }**/*//1/1//-*T/*——u/T///.KBU, 43 4.60 4.80 5.00 5.20 5.40 m/z 55.00 30.70% 5000 70 41 30

n/z-> 01 more... I|. 20 25 . 30 + 68 72 38 ■ । . 11 ■ 35 40 45 50 55 60 65 70। 75 80 1 • 1 ■ ■ i ■ ' i 1 ' ‘ ‘ 1 1 1 1 1 1 1 1 1 1 1 1 1 '■ 1 1 1 r ' ’ ' ' l ‘ ' 4.60 4.80 5.00 ,1 1 >i । I ■ i 5.20 5.40

02714.D HP022102.M Fri Mar 01 10:07:01 2002 Page 8

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