GCMS analysis results for sample AE03246, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02MAR01\03246.D Vial: 1 Acq On : 1 Mar 2002 4:00 pm Operator: Sample : 508 scan Inst : Instrumen Mise : March 1, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library- : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 7 DEUTEROACETONE Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

5.02 0.11 ug/L 54064 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 DEUTEROACETONE 59 C3H5DO 004468-52-4 9 2 1-Hexene, 4,5-dimethyl- 112 C8H16 016106-59-5 9 3 3-Hexen-2-one, 5-methyl- (CAS) $... 112 C7H12O 005166-53-0 9 4 Imidazole-2,4,5-d3 $$ IH-Imidazo... 71 C3HD3N2 006745-43-3 7 Abundance Scan 146 (5.022 min): 03246.D (-) m/z 71.00 100.00% 43 71

5000

0- • ■ । ■ 1 1 ■ । 1 ■ ■ ■ i ■ 1 1 1 । 1 4ll 53 59

■ ■ i ■ ■ ■ । i ■ ■ ■ ■ । ■ i ‘ ■ i 1 4.60 i i ' ' ' ■ i ' 1

m/z 4.80 43.10 5.00 5.20 5.40 89.06% m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #587: DEUTEROACETONE 4

59 \ MAw A W! AW/ , A 5000 4.60 4.80 5.00 5.20 5.40 m/z 41.10 71.33%

n/z-> 0- --344 10 20 30 40 ,mmm 50 60 70 80 90 100 110 Abundance #13810: 1-Hexene, 4,5-dimethyl- 43

4.60 A JAAAA —4.80 A 5.20 5.40 5.00 i4 1 71 5000 m/z 59.00 34.95% 27 55 15

m/z—> 0- 1 t40 50 60 1 ' i ■ ■ 1 1 i 1 70 80 90 ,I , ■ ■ ■ r> । ।

100 110 84 । । i ‘ ‘ । 97 । । 112। । ‘ । ।

Abundance 10 20 30 #13394: 3-Hexen-2-one, 5-methyl- (CAS) $$ 5-METHYL-HEXA-3-... A , , , I ) 0. A , 43 4.60 4.80 5.00 5.20 5.40 m/z 55.10 34.32%

y.. 5000 15 27 69 53 38 . — 1 I'''1 ■ 1 | ■>> ‘ । | !> 1 I | I I I I | ■ I I ' | I I > I | I I I I | 0- ■ ■ i - ■ ■ ■ । ■ I 1 i ■ ■ ■' 1 । । A 1dT 1 1 1 1 1 ' I 1 ' 1 ' I ' ' 1 ' 1 1 ' m/z-> 10 20 30 40 50 60 70 80 90 100 110 4.60 4.80 5.00 5.20 5.40

03246.D HP022102.M Mon Mar 04 12:33:13 2002 Page 9

NYC-WTC_000006117