GCMS analysis results for sample AE01638, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report , , Data File : C:\MSDCHEM\1\5973N\02FEB21\01638.D Vial: 7 Acq On : 21 Feb 2002 8:11 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 6 Pyrimidinetetramine- $$ Pyr... Concentration Rank 8 R.T. EstConc Area Relative to ISTD R.T. 13.38 0.05 ug/L 39524 Naphthalene-d8 13.20 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Pyrimidinetetramine- $$ Pyrimidi... 140 C4H8N6 001004-74-6 56 2 2,5-Diamino-6-methyl-4-pyrimidinol 140 C5H8N40 000000-00-0 9 3 1-ETHYL-4,5-DIMETHYL-4-IMIDAZOLI... 140 C7H12N20 059167-88-3 9 4 M-(METHYL THIO)PHENYL ESTER OF M... 197 C9H11NO2S 000000-00-0 9 Abundance Scan 886 (13.376 min): 01638.D (-) m/z 140.00 100.00% 1-0

5000

TT T "P If

miz-> 01 —74 40 50 60 70 80 90 f 108 ------- 100 110 120 130 140 I ■ ■ ■ • i 1300 13.20 13.40 13.60 13.80 m/z 94.10 12.78% Abundance #35040: Pyrimidinetetramine- $$ Pyrimidine. 2,4,5,6-tetraa... 140

5000 1 ■ i • ■ ■ ■ i ■ TTAPTmmr 13.00 13.20 13.40 13.60 13.80 44 71 123 m/z 70.00 10.04%

n/z-> 01 50 60 70 M 86 96 112 1 1 I 1 1 । 1 i ■ ■ ''I i 1 1 1 1 I I1' 1 1 I 11 ' 1 1 1 1 , | 80 90 100 110 120 130 140 ’II

Abundance #35088:2,5-Diamino-6-methyl-4-pyrimidinol 140 ----------------- 13.00 13.20 13.40 13.60 13.80 5000 m/z 141.00 8.18%

42 70 1 54 . 95 111 123 Ot * > > j i i ■ > I i 1 « > j * ■ ' 1T' 00 —1, TI m/z—> 40 50 60 70 80 90 100 110 120 130 140 Abundance #35417:1-ETHYL-4,5-DIMETHYL-4-IMIDAZOLIN-2-ONE $$ 2H-Imid... ' 1 i ■ ■ ■ ■ i ■ ■ i 1 1 ■ ■ i ■ • 140 13.00 13,20 13.40 13.60 13.80 111 m/z 96.10 8.15%

5000 97 68 125 84 /z-> 0: 40 50 60 70 r r +' ■ I ■ ' 80 90 l ■ 100 I 110 0 120 130 140 • ■ • • i ■ i ■ ■ ‘ 1 i ‘ ‘ ' 1 i 1 ■ ' ‘ i ■ 13.00 13.20 13.40 13.60 13.80

01638.D HP022102.M Mon Feb 25 10:55:51 2002 Page 8

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