GCMS calibration analysis results, DEP Labs, Feb 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02FEB21\0123B.D Vial: 1 Acq On : 21 Feb 2002 10:46 am Operator: Sample : lab blank 1/23 Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L Peak Number 8 5-Pyrazolidone Concentration Rank 13 R.T. EstConc Area Relative to ISTD R.T.

14.54 0.02 ug/L 14076 Naphthalene-d8 13.20 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 5-Pyrazolidone 86 C3H6N20 000000-00-0 4 2 3-Butenoic acid (CAS) $$ Vinylac... 86 C4H602 000625-38-7 4 3 Acetic acid ethenyl ester (CAS) ... 86 C4H602 000108-05-4 4 4 3-Butenoic acid $$ .beta.-Buteno... 86 C4H602 000625-38-7 4 Abundance Scan 989 (14.539 min): 0123B.D (-) m/z 83.90 100.00% 44 84 MyAupopMAAoM N 5000 49 • • j > * I IIFIIIIIIIt 14.20 14.40 14.60 14.80 01 11t 111111‘111111111111/111111/1/-.7113. m/z 86.00 92.16% miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #3718:5-Pyrazolidone 27

44 86 5000 55 ■ ‘i ’ 1 r 1 1 1 1 i ' ■'' f 30 14.20 14.40 14.60 14.80 m/z 44.00 89.36% Of / niz-> 20 25 ’ 141+41’1 i ■ ■' • i ■ ■ 30 35 40 45 50 55 60 65 70 75 80 85 1' ■ I'■■■i■ 90 95 AMWW/ N N W/ Abundance #3751: 3-Butenoic acid (CAS) $$ Vinylacetic acid $$ .beta.... 39

14.20 14.40 14.60 14.80 5000 12 m/z 49.00 30.67%

Of ■ • i1 ■1111 ■ ■41 ‘ ■ i ■ TImP 45 58 86 WwMobyMonw n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #3791: Acetic acid ethenyl ester (CAS) $$ Vinyl acetate $$... 43 14.20 14.40 14.60 14.80

5000

86 40 0 ■' i1 ‘ " i1 " • i ■ ■ " i " ■' 11 I ''' ' I ' ‘ ' I ' ''' I ' ‘‘ I " ' ‘ I ‘1' ‘ I “ '' 11 ‘ " I "■I""!1 n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95

0123B.D HP022102.M Mon Feb 25 10:54:37 2002 Page 10

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