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GCMS calibration analysis results, DEP Labs, Feb 2002

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Calibration data for GCMS analysis using 625/TCLP method with deuterated compound reference standards recorded on February 21, 2002.

NYC-WTC_000009835–000009850

Folder label: “GCMS X 1/22/02 A 2/22/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\FEB2102\472.D Vial: 6 Acq On : 21 Feb 2002 7:01 pm Operator: Sample : gc/ms scan 1/22 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 6 Phenethylamine, N-methyl-.beta Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

23.46 0.56 ug/1 54883 Acenaphthene-dl0 21.29

Hit# of 5 Tentative ID MW MolForm CAS# Qual

I Phenethylamine/ N-methyl-.beta.,3,4 399 C18H37NO3Si3 010538-85-9 43 2 Benzoic acid, 2,4-bis[(trimethylsil 370 C16H30O4Si3 010586-16-0 38 3 Benzeneethanamine, N-[ (pentafluorop 563 C24H34F5NO3Si3 055429-13-5 37 4 Noradrenal in tetra-TMS 457 C20H43N03Si4 000000-00-0 37 Abundance 73 Scan 2006 (23.456 min): 472.D (-) ............................... m/ z 72.95.... 100.0 0 %

5000 355 147 221 ...... 281 45 I 327 401 23.20 23.40 23.60 23.80

m/z-> —— 50 100 150 200 250 300 350 400 kon) ... . 450 500 550 m/z 355.05 39.36% Abundance #74239: Phenethylamine, N-methyl-.beta,,3,4-tris(trimethyls 73

......... .... 5000 355 23.20 23.40 23.60 23.80 44 m/z 147.00 31.59% j b 147 193 267 294 m/z->50. JOO . 150.200.. 250. 300 350 400 450 500 . 550 Abundance * . * 73

23.20 23.40 23.60 23.80 5000 355 m/z 221.05 21.80% 45 133 193 223 281 m/z-> 50 100 150 200 250 300 350 400 450 500 550 Abundance #74706: Benzeneethanamine, N-[(pentafluoropheny!)methylene] 73 355 23.20 23.40 23.60 23.80 m/z 281.00 18.78% 5000

45 251.281 208 386 458 548 ■ ■ i ‘ ' miz-> 50 100 150 200 250 300 350 400 450 500 550 23.20 23.40 23.60 23.80

472.D GCMS0208.M Fri Feb 22 09:42:34 2002 Page 6

NYC-WTC_000009844

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NYC-WTC_000009844Source: NYC Law Department, mirrored locally

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