GCMS calibration analysis results, DEP Labs, Feb 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\FEB210 2\CAI D Vial: 2 Acq On 21 Feb 2002 2:06 pm Operator: Sample Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 22 8:36 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Thu Feb 21 16:13:52 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.35 152 288182 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 1099667 20.00 ug/1 0.00 17) Acenaphthene-diO 21.30 164 607829 20.00 ug/1 -0.02 29) Phenanthrene-diO 25.74 188 872026 20.00 ug/1 -0.02 38) Chrysene-dl2 33.82 240 582252 20.00 ug/1 -0.02 44) Perylene-dl2 38.09 264 382469 20.00 ug/1 -0.03

System Monitoring Compounds 37) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.96 74 539439 46.78 ug/1 # 71 3) bis(2-Chloroethyl)ether 11.75 93 804502 42.47 ug/1 94 4) 1,3-Dichlorobenzene 12.25 146 853139 37.84 ug/1 99 5) 1,4-Dichlorobenzene 12.39 146 857090 37.30 ug/1 99 6) 1,2-Dichlorobenzene 12.91 146 793255 36.33 ug/1 99 7) 2,2'-oxybi s(1-Chioropropan 13.23 45 1147214 40.01 ug/1 98 8) N-Nitroso-di-n-propylamine 13.63 70 549127 40.52 ug/1 # 85 9) Hexachloroethane 13.75 117 316590 34.42 ug/1 95 11) Nitrobenzene 14.04 77 800560 35.40 ug/1 96 12) 1sophorone 14.69 82 1561227 40.87 ug/1 99 13) bis(2-Chloroethoxy)methane 15.37 93 959037 40.31 ug/1 99 14) 1,2,4-Trichlorobenzene 15.87 180 678964 36.08 ug/1 98 15) Naphthalene 16.05 128 2130117 36.37 ug/1 99 16) Hexachlorobutadiene 16.59 225 353085 31.35 ug/1 99 18) Hexachlorocyclopentadiene 18.78 237 280303 32.21 ug/1 99 19) 2-Chloronaphthalene 19.55 162 1335913 36.86 ug/1 97 20) Dimethylphthalate 20.66 163 1584966 37.55 ug/1 99 21) 2,6-Dinitrotoluene 20.87 165 382424 39.98 ug/1 # 84 22) Acenaphthylene 20.83 152 1954465 37.33 ug/1 99 2 3) Acenaphthene 21.40 153 1335293 36.49 ug/1 99 24) 2,4-Dinitrotoluene 22.04 165 494195 40.78 ug/1 # 79 25) Diethylphthalate 22.79 149 1563607 35.65 ug/1 97 26) 4-Chlorophenyl-phenylether 22.93 204 654416 34.66 ug/1 96 27) Fluorene 22.92 166 1433501 35.90 ug/1 100 28) Azobenzen/ 1,2-Diphenylhyd 23.41 77 1606687 34.82 ug/L # 86

(#) = qualifier out of range (m) = manual integration CAL40.D GCMS0208.M Fri Feb 22 08:37:16 2002 Page 1

NYC-WTC_000009817