GCMS analysis results for sample AE02646, Mar 15, 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File C: \HPCHEM\ 1 \DATA\MARO 702\2646.D Vial: 19 Acq On 8 Mar 2002 7:26 am Operator: Sample gc/ms scan 2/5 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 5 Benzoic acid, ethyl ester Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

33.45 0.37 ug/1 61992 Chrysene-dl2 33.76

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Benzoic acid; ethyl ester 150 C9H10O2 000093-89-0 16 2 1-Propanone, 2,2-dimethyl-l-phenyl- 162 C11H14O 000938-16-9 16 3 3 -Buten-2-ol , benzoate 176 C11H1202 065001-62-9 16 4 1-Benzoyloxy-2-formyloxybenzene 242 C14H10O4 797922-93-1 16 Abundance Scan 3095 (33.455 min): 2646.D (-) m/z 104.95.’100.00% 1 15 149

5000 77

51 33.20 33.40 33.60 33.80 43 | , 163 207 TTIITWTTOTTTIPTTTT —m— m/z 149.00 79.83% m/z-_ Abundance 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 #66754: Benzoic acid, ethyl ester 105

........... ) . 001 ./ 5000 77 122 33.20 33.40 33.60 33.80 51 150 m/ z 77.00 37.16%

m/z-> 40 ‘I‘ | ‘ i' ■'' l " " i |. 91. 1. 135 | " ' l " " i " 1' I " " i''1 ‘ i' ■' ■ i ‘" i " " I" " i " 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 Abundance 105 —TP 33.20 33.40 33.60 33.80 5000 m/z 150.00 10.77% 77 57 91 119 162 m/z-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 Abundance #16714: 3-Buten-2-ol, benzoate ite 33.20 33.40 33.60 33.80 m/z 51.0.0 10.22% 5000 77

m/z-> "III 40 MH 51 . , 1 123131 147 161 176 hur......... I"1 1' i " " i11" " r ■ " i " ■ ’I’ ■ 111111111 ITTH. 11111111111 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 ■ ' i ' ' 33.20 4 33.40 33.60 33.80

2646.D GCMS0208.M Wed Mar 13 14:56:38 2002 Page 5

NYC-WTC_000005446