DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\l\5973N\02FEB27\02387.D Vial: 3 Acq On : 27 Feb 2002 4:57 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 27, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 9 5-Fluoronicotin amide Concentration Rank 8

R.T. EstConc Area Relative to ISTD R.T. 13.38 0.07 ug/L 41242 Naphthalene-d8 13.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 5-Fluoronicotin amide 140 C6H5FN20 000000-00-0 39 2 2-Fluoronicotinamide 140 C6H5FN20 000364-22-7 39 3 4(1H)-Pyrimidinone, 2-amino-6-(m... 140 C5H8N40 054004-20-5 9 4 l-Oxetan-2-one, 4,4-diethyl-3-me... 140 C8H12O2 000000-00-0 9 Abundance Scan 886 (13.375 min): 02387.D (-) m/z 140.00 100.00% 140

5000 .............. .................................. , 54 70 94 13.00 13.20 13.40 13.60 13.80

•n/z-> Of -1’11' 40 494 50 60 70 80 84..... 108 90 ' 1 I ' 1 ‘"'"I 1IIIII 100 110 —1 1I 120 130 140 m/ z 70.00 13.30% Abundance #35137:5-Fluoronicotin amide 140

96 5000 124 ■ i ■ 1 1 1 i ■ r 13.00 13.20 13.40 13.60 13.80 44 69 76 m/ z 94.00 13.25% 50 O+ 1 1 1 1 - I............................. , r i ■ ■ ' ■ i 1 1 1 1 i 1 1 ' । 1 1 +1 1II miz-> 40 50 60 70 80 90 100 110 120 130 140 Abundance #35138: 2-Fluoronicotinamide 124 1-0 ------- 96 13.00 13.20 13.40 13.60 13.80 5000 m/ z 54.10 12.77% 44 51 70 76

m/z-> o! ' 1 i ' 40 -mmm 50 60 70 ' i ' ‘ ' ■ i ' ' 80 90 100 110 120 130 I 1 1 i 1 ' —L TTI 140 Abundance #35078:4(1 H)-Pyrimidinone, 2-amino-6-(methylamino)- ,.................... 140 13.00 13.20 13.40 13.60 13.80 m/z 141.00 9.39% 44 5000 111 70 82 97 .

m/z—> 0 ■ ' i ‘ 40 1 ■ । ■ 1 ' ■ । ■ r 50 60 70 80 1.... 90 ill100.....110Il........... 1 120 130 140 TT 13,00 13.20 13.40 13.60 13.80

32387.D HP022102.M Thu Feb 28 08:47:17 2002 Page 11

NYC-WTC_000005060